Chemical vapour deposition (CVD) is a powerful technology for producing high-quality solid thin films and coatings. While widely used in modern industries, it is continuously being developed as it is adapted to new materials. Today, CVD synthesis is being pushed to new heights with the precise manufacturing of both inorganic thin films of two-dimensional (2D) materials and high-purity polymeric thin films that can be conformally deposited on various substrates. In this Primer, an overview of the CVD technique including instrument construction, process control, material characterization, and reproducibility issues is provided. By taking graphene, 2D transition metal dichalcogenides (TMDs) and polymeric thin films as typical examples, the best practices for experimentation involving substrate pre-treatment, hightemperature growth and post-growth processes are presented. Recent advances and scaling-up challenges are also highlighted. By analyzing current limitations and optimizations, we also provide insight into possible future directions for the method, including reactor design for highthroughput and low-temperature growth of thin films.
From a device application point of view, the extreme mechanical strength of graphene is highly desirable. However, the unavoidable polycrystalline nature of graphene films produced by chemical vapor deposition (CVD) leads to significant fluctuations in mechanical properties. Although the effects of atomic defects or grain boundaries (GBs) on mechanical strength have been widely studied and some modifications have been applied to enhance the stiffness of graphene, the problems of fragility as well as significantly reduced breaking strength arise. Here we report a systematic study on the effect of elastic modulus and breaking strength of CVD-derived graphene films with a controlled density and distribution of GBs. We find that graphene films become much stronger by hugely increasing the density of GBs without triple junctions (TJs) formed inside, in analogy to the two-dimensional (2D) plum pudding structures. The comprehensive performance with a 2D Young's modulus of 436 N/m (∼1.3 TPa) and 2D breaking strength of 43 N/m (∼128 GPa) can be achieved with the average grain size of 20 nm. Moreover, the existence of TJs will slightly reduce the strength in these GB structures. Due to defect types, the graphene films will show various tearing behaviors after indentation. All these mechanical studies of GBs provide a guideline to obtain the optimal performance of 2D materials through GB structure engineering.
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