Highly adherent wettability patterns on the substrate-independent superhydrophobic surfaces of trimethoxyoctadecylsilane modified titanium dioxide (TiO)-based coatings were prepared by using commercial photolithography. Three custom unidirectional channels with gradient wettability patterns were obtained by spatially selective wettability conversion from superhydrophobic to superhydrophilic when the coatings were exposed to ultraviolet light (∼365 nm). The movement behavior of droplets on these unidirectional channels was studied and the displacement of droplet movement was effectively controlled. Integrating the idea of gradient wettability patterns into planar microfluidic devices (microreactors), a self-driven fluid transport was achieved to realize droplet metering, merging or reaction, and rapid transport. This self-driven fluid transport with gradient wettability patterns has great potential in fabricating a new category of pump-free microfluidic systems that can be used in various conditions.

The wetting transition on submersed superhydrophobic surfaces with hierarchical structures and the influence of trapped air on superhydrophobic stability are predicted based on the thermodynamics and mechanical analyses. The dewetting transition on the hierarchically structured surfaces is investigated, and two necessary thermodynamic conditions and a mechanical balance condition for dewetting transition are proposed. The corresponding thermodynamic phase diagram of reversible transition and the critical reversed pressure well explain the experimental results reported previously. Our theory provides a useful guideline for precise controlling of breaking down and recovering of superhydrophobicity by designing superhydrophobic surfaces with hierarchical structures under water.

The Venus flytrap takes advantage of its bistability to generate rapid closure motion for capturing its prey. A bioinspired Venus flytrap robot with bistable artifical leaves is presented in this paper. Non-contact electromagnetic driving method is proposed to actuate the Venus flytrap robot's artifical leaves, which are made of anti-symmetric carbon fiber reinforced prepreg (CFRP) cylindrical shells. Magnetic force is generated by using the electromagnet and applied on the shell's curve edge to unbend the shell, and then the bending process transmits from one edge to the whole surface. The required magnetic force for the snap-through process of the bistable CFRP structure is determined from experimental test and compared with the result of finite element simulation. The test of the snap-through process of the Venus flytrap robot show that the Venus flytrap robot can generate a rapid snapping motion by the electromagnet actuation.

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