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The Moroccan cement industry is looking for new processes to effectively minimize the high energy costs associated to cement manufacturing. This work presents the effect of three types of limestone with different chemical compositions and different CaCO3 contents on the physical and mechanical properties of resulting composite cements by the addition of fly ash in the proportions by weight of: 5 % and 10 %. The samples are studied in order to evaluate the interaction between different types of limestone and fly ash. Ternary cements based on fly ash-limestone-clinker induce a significant prolongation of the setting time compared to binary cements based on limestone-clinker. The substitution of clinker by limestone induces an improvement in mechanical strength compared to ternary cements in the first days; at 28 days, cements prepared with fly ashes reach significant strength due to their pozzolanic reaction.

Layered Double Hydroxide (LDH) is ionic clay that is characterized by the union of metal cations and OH- hydroxides. LDH composites exhibit considerably high releasing and recharging capacity and have applications as bioactive cements. They can be prepared by direct co-precipitation of metal salts at controlled pH. The preparation is carried out from an acid solution of Zn (NO3)2.6H2O, Al (NO3)3.9H2O and a basic solution of Na2CO3 and NaOH, with a Zn/Al ratio = 3, the pH is stabilized between 9 and 9.5 at a constant temperature of 45°C. The objective of this study is to incorporate Zinc and Aluminum elements at different percentages in dicalcium silicate phase to produce C2S phase incorporating LDH composite. The characterizations of the developed phases by XRD and SEM indicate the formation of stoichiometric LDH phases Zn6Al2(OH)16CO3.4H2O and non-stoichiometric Zn0.61Al0.39 (OH)2(CO3)0.195.xH2O, the incorporation of Zn in the belitic C2S phase and not Al. The obtained micrographs by SEM(EDAX) analysis show new morphology of the stabilized composite.