In a previous paper, various properties of the mixture acetic acid + triethylamine were investigated and explained in terms of a very strong attractive interaction between a 1:1 complex acid + amine and the cyclic dimer of acetic acid, leading to a 3:1 aggregate of extreme thermodynamic stability. This gives rise to phase separation at negative values of the excess Gibbs energy. In the present series of articles, an attempt is made to present a unified treatment of systems of carboxylic acid + amine, with emphasis on triethylamine, but with inclusion of some recent results involving the tri-n-butylamine as well as secondary and primary n-butylamine. In this paper we present experimental results on solid-liquid equilibria of formic, propionic, and trimethylacetic (pivalic) acids + triethylamine and viscosities of formic, trifluoroacetic, propionic, and trimethylacetic acids + triethylamine, propionic and trimethylacetic acids + tri-n-butylamine, propionic acid + di-n-butylamine, and propionic acid + n-butylamine.

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Melting curves, viscosities and densities have been determined for the mixtures of 1,2,4‐trichlorobenzene + n‐decane and + n‐tetradecane. Derived thermodynamic excess properties (excess Gibbs energy gE and excess volume vE) can be combined with literature data on trichlorobenzene + n‐alkane systems to establish an unusual trend of mixing properties with chain length of n‐alkane. Also viscosities of equimolar mixtures of trichlorobenzene with various n‐alkanes and of benzene with various n‐alkanes have been measured, in order to collect more material on the behaviour of n‐alkane mixtures.

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