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The presence of solid carbonaceous matter in cometary dust was established by the detection of elements such as carbon, hydrogen, oxygen and nitrogen in particles from comet 1P/Halley. Such matter is generally thought to have originated in the interstellar medium, but it might have formed in the solar nebula-the cloud of gas and dust that was left over after the Sun formed. This solid carbonaceous material cannot be observed from Earth, so it has eluded unambiguous characterization. Many gaseous organic molecules, however, have been observed; they come mostly from the sublimation of ices at the surface or in the subsurface of cometary nuclei. These ices could have been formed from material inherited from the interstellar medium that suffered little processing in the solar nebula. Here we report the in situ detection of solid organic matter in the dust particles emitted by comet 67P/Churyumov-Gerasimenko; the carbon in this organic material is bound in very large macromolecular compounds, analogous to the insoluble organic matter found in the carbonaceous chondrite meteorites. The organic matter in meteorites might have formed in the interstellar medium and/or the solar nebula, but was almost certainly modified in the meteorites' parent bodies. We conclude that the observed cometary carbonaceous solid matter could have the same origin as the meteoritic insoluble organic matter, but suffered less modification before and/or after being incorporated into the comet.

The ESA mission Rosetta, launched on March 2nd, 2004, carries an instrument suite to the comet 67P/Churyumov-Gerasimenko. The COmetary Secondary Ion Mass Anaylzer -COSIMA -is one of three cometary dust analyzing instruments onboard Rosetta. COSIMA is based on the analytic measurement method of secondary ion mass spectrometry (SIMS). The experiment's goal is in-situ analysis of the elemental composition (and isotopic composition of key elements) of cometary grains. The chemical characterization will include the main organic components, present homologous and functional groups, as well as the mineralogical and petrographical classification of the inorganic phases. All this analysis is closely related to the chemistry and history of the early solar system. COSIMA covers a mass range from 1 to 3500 amu with a mass resolution m/ m @ 50% of 2000 at mass 100 amu. Cometary dust is collected on special, metal covered, targets, which are handled by a target manipulation unit. Once exposed to the cometary dust environment, the collected dust grains are located on the target by a microscopic camera. A pulsed primary indium ion beam (among other entities) releases secondary ions from the dust grains. These ions, either positive or negative, are selected and accelerated by electrical fields and travel a well-defined distance through a drift tube and an ion reflector. A microsphere plate with dedicated amplifier is used to detect the ions. The arrival times of the ions are digitized, and the mass spectra of the secondary ions are calculated from these time-of-flight spectra. Through the instrument commissioning, COSIMA took the very first SIMS spectra of the targets in space. COSIMA will be the first instrument applying the SIMS technique in-situ to cometary grain analysis as Rosetta approaches the comet 67P/Churyumov-Gerasimenko, after a long journey of 10 years, in 2014.

The COmetary Secondary Ion Mass Analyser instrument on board ESAʼs Rosetta mission has collected dust particles in the coma of comet 67P/Churyumov-Gerasimenko. During the early-orbit phase of the Rosetta mission, particles and particle agglomerates have been imaged and analyzed in the inner coma at distances between 100 km and 10 km off the cometary nucleus and at more than 3 AU from the Sun. We identified 585 particles of more than 14 μm in size. The particles are collected at low impact speeds and constitute a sample of the dust particles in the inner coma impacting and fragmenting on the targets. The sizes of the particles range from 14 μm up to submillimeter sizes and the differential dust flux size distribution is fitted with a power law exponent of −3.1. After impact, the larger particles tend to stick together, spread out or consist of single or a group of clumps, and the flocculent morphology of the fragmented particles is revealed. The elemental composition of the dust particles is heterogeneous and the particles could contain typical silicates like olivine and pyroxenes, as well as iron sulfides. The sodium to iron elemental ratio is enriched with regard to abundances in CI carbonaceous chondrites by a factor from ∼1.5 to ∼15. No clear evidence for organic matter has been identified. The composition and morphology of the collected dust particles appear to be similar to that of interplanetary dust particles.

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