This study investigated the effect of a 30% hydrogen peroxide bleaching agent on bovine enamel in terms of mineral loss. Contents of mineral elements both in the teeth and bleaching agent were evaluated to estimate the effect of hydrogen peroxide on teeth. Finely polished non-carious bovine incisors (n = 5) were immersed in a 30% hydrogen peroxide solution for 120 h. The amounts of concentrated elements in the bleaching agent (5 mL) were measured using inductively coupled plasma-atomic emission spectrometer and ion chromatograph. The contents of mineral elements in the teeth were measured using an electron probe microanalyzer. The Ca/P ratio in the bleaching agent was approximately 1.99. The amount of Zn in the bleaching agent was below the detection limit. The total content of mineral elements of the unbleached enamel (90.75 +/- 1.58) was slightly greater than that of the bleached enamel (87.44 +/- 0.77). The Ca/P ratio of the bleached enamel was 2.06. The amount of Ca loss from the bleached enamels after 120 h was similar to the amount of Ca loss from teeth exposed to a soft drink or juice for a few minutes. Therefore, mineral loss caused by the bleaching process may not be a threatening factor to teeth.
The use of bleaching agents has become a popular procedure for whitening teeth. Recently introduced polyacid-modified composite resins (compomers) have several favorable features, such as improved physical properties and fluoride release. Because these two materials have many possibilities to interact in the oral cavity during dental treatment, it is necessary to understand such interaction. To evaluate the effect of a bleaching agent on dental restoratives, three compomers were photopolymerized and then bleached for 1, 2, 3 and 5 days with the use of 30% hydrogen peroxide. Fluoride release, surface microhardness, and surface modifications were evaluated. It was found that the cumulative fluoride release was found to be linearly correlated to the tested periods of bleaching in all compomers. Among the tested compomers, F2000 showed the highest cumulative fluoride release. Bleached compomers became soft because of surface degradation, so the surface microhardness decreased. F2000 showed an apparent crack formation that was not observed in other compomers. The nearly linear correlation between the filler content and microhardness was found in the control samples. However, the same correlation was not observed after the compomers were stored in a bleaching agent or distilled water.
Fluoride-containing restorative materials are frequently utilized to delay or inhibit caries. The quality of the fluoride-containing composite resins was evaluated by testing their microhardness, polymerization shrinkage, thermal expansion coefficient, and surface morphology. Some of them were evaluated in conjunction with the thermocycling process. The microhardness values of the thermocycled specimens were similar to those of the specimens immersed only in distilled water. Among the specimens, Surefil showed the highest (68.6 +/- 1.2 Hv) value. A linear correlation was found between microhardness and the filler content (vol%) of the specimens regardless of their states. Polymerization shrinkage rapidly increased during the light curing, and then it reached a plateau. The shrinkage values increased as the specimens became thicker. In a temperature range of 30 approximately 80 degrees C, the coefficients of thermal expansion of the control specimens ranged between 43 x 10(-6)/ degrees C and 77 x 10(-6)/ degrees C. An inverse correlations were observed between the filler content (vol%) and the coefficient of thermal expansion and between microhardness and the coefficient of thermal expansion of the control specimens. Tetric Ceram showed a perforated or "Swiss-cheese" morphology after thermocycling. It was unique and occurred only in this product.
The aim of this study was to make clear the age-hardening mechanism in a dental high carat gold alloy. For this purpose, age-hardening behaviour of a commercial dental high carat gold alloy, 65.5 wt% Au-14.0 wt% Ag-10.0 wt% Cu-8.9 wt% Pt, was investigated by means of hardness testing, X-ray diffraction study and scanning electron microscopy. Age-hardening was generated by the coherency strain resulting from the transformation of the alpha single phase to the Ag-rich alpha 1 phase and the AuCu I type ordered phase. The coherency strain seemed to be associated with the nucleation of the AuCu ordered structure initially, and then was brought about with the simultaneous formation of the Ag-rich alpha 1 phase and the AuCu I type ordered phase. Hardening was attributed mainly to the very fine coherent precipitates of a lamellar structure composed of the Ag-rich alpha 1 phase and the AuCu I type ordered phase at grain boundaries, and softening, which occurred following prolonged ageing, was due to the coarsening of the fine lamellar structure by releasing the strain at the interfaces of the adjacent lamellae.
The interaction between bleaching agents and recently introduced compomers has several issues that need to be explored, including morphology and mechanical properties. To investigate the effect of 30% hydrogen peroxide, a bleaching agent, on the color of compomers, three compomers (Compoglass F, Elan, and F2000) were polymerized, bleached up to 120 h, and then measured to determine the reflectance of the specimen during the bleaching process. Color differences were evaluated from the reflectance and color values that were represented by CIE L*a*b* values. Compomers stored in distilled water were used as a source of reference. Teeth were also used for comparison. Color differences for both the tested teeth and compomers and different periods of bleaching and soaking in distilled water showed statistically significant difference (p < 0.0001). Among the tested compomers, Compoglass F demonstrated the highest color difference. In addition, the color differences were maximal during the first 24 h. After 24 h, the color difference increased nearly linearly. Compomers stored in both a bleaching agent and distilled water did not exhibit much color difference between them. However, the color difference between teeth and compomers was considerable.
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