Context. KELT-9 b exemplifies a newly emerging class of short-period gaseous exoplanets that tend to orbit hot, early type stars – termed ultra-hot Jupiters. The severe stellar irradiation heats their atmospheres to temperatures of ~4000 K, similar to temperatures of photospheres of dwarf stars. Due to the absence of aerosols and complex molecular chemistry at such temperatures, these planets offer the potential of detailed chemical characterization through transit and day-side spectroscopy. Detailed studies of their chemical inventories may provide crucial constraints on their formation process(es) and evolution history. Aims. We aim to search the optical transmission spectrum of KELT-9 b for absorption lines by metals using the cross-correlation technique. Methods. We analysed two transit observations obtained with the HARPS-N spectrograph. We used an isothermal equilibrium chemistry model to predict the transmission spectrum for each of the neutral and singly ionized atoms with atomic numbers between three and 78. Of these, we identified the elements that are expected to have spectral lines in the visible wavelength range and used those as cross-correlation templates. Results. We detect (>5σ) absorption by Na I, Cr II, Sc II and Y II, and confirm previous detections of Mg I, Fe I, Fe II, and Ti II. In addition, we find evidence of Ca I, Cr I, Co I, and Sr II that will require further observations to verify. The detected absorption lines are significantly deeper than predicted by our model, suggesting that the material is transported to higher altitudes where the density is enhanced compared to a hydrostatic profile, and that the material is part of an extended or outflowing envelope. There appears to be no significant blue-shift of the absorption spectrum due to a net day-to-night side wind. In particular, the strong Fe II feature is shifted by 0.18 ± 0.27 km s−1, consistent with zero. Using the orbital velocity of the planet we derive revised masses and radii of the star and the planet: M* = 1.978 ± 0.023 M⊙, R* = 2.178 ± 0.011 R⊙, mp = 2.44 ± 0.70 MJ and Rp = 1.783 ± 0.009 RJ.

To constrain the formation history of an exoplanet, we need to know its chemical composition. With an equilibrium temperature of about 4,050 kelvin, the exoplanet KELT-9b (also known as HD 195689b) is an archetype of the class of ultrahot Jupiters that straddle the transition between stars and gas-giant exoplanets and are therefore useful for studying atmospheric chemistry. At these high temperatures, iron and several other transition metals are not sequestered in molecules or cloud particles and exist solely in their atomic forms. However, despite being the most abundant transition metal in nature, iron has not hitherto been detected directly in an exoplanet because it is highly refractory. The high temperatures of KELT-9b imply that its atmosphere is a tightly constrained chemical system that is expected to be nearly in chemical equilibrium and cloud-free, and it has been predicted that spectral lines of iron should be detectable in the visible range of wavelengths. Here we report observations of neutral and singly ionized atomic iron (Fe and Fe) and singly ionized atomic titanium (Ti) in the atmosphere of KELT-9b. We identify these species using cross-correlation analysis of high-resolution spectra obtained as the exoplanet passed in front of its host star. Similar detections of metals in other ultrahot Jupiters will provide constraints for planetary formation theories.

KELT-9 b, the hottest known exoplanet, with Teq ~ 4400 K, is the archetype of a new planet class known as ultra-hot Jupiters. These exoplanets are presumed to have an atmosphere dominated by neutral and ionized atomic species. In particular, Hα and Hβ Balmer lines have been detected in the KELT-9 b upper atmosphere, suggesting that hydrogen is filling the planetary Roche lobe and escaping from the planet. In this work, we detected δ Scuti-type stellar pulsation (with a period Ppuls = 7.54 ± 0.12 h) and studied the Rossiter-McLaughlin effect (finding a spin-orbit angle λ = −85.01° ± 0.23°) prior to focussing on the Balmer lines (Hα to Hζ) in the optical transmission spectrum of KELT-9 b. Our HARPS-N data show significant absorption for Hα to Hδ. The precise line shapes of the Hα, Hβ, and Hγ absorptions allow us to put constraints on the thermospheric temperature. Moreover, the mass loss rate, and the excited hydrogen population of KELT-9 b are also constrained, thanks to a retrieval analysis performed with a new atmospheric model. We retrieved a thermospheric temperature of T = 13 200−720+800 K and a mass loss rate of Ṁ = 1012.8±0.3 g s−1 when the atmosphere was assumed to be in hydrodynamical expansion and in local thermodynamic equilibrium (LTE). Since the thermospheres of hot Jupiters are not expected to be in LTE, we explored atmospheric structures with non-Boltzmann equilibrium for the population of the excited hydrogen. We do not find strong statistical evidence in favor of a departure from LTE. However, our non-LTE scenario suggests that a departure from the Boltzmann equilibrium may not be sufficient to explain the retrieved low number densities of the excited hydrogen. In non-LTE, Saha equilibrium departure via photo-ionization, is also likely to be necessary to explain the data.