Coexistence of the ferroelectric polarization and spontaneous magnetization has been found in Y-type hexaferrite Ba2Mg2Fe12O22. The reversal of magnetization by a small magnetic field below ∼0.02 T accompanies an electric polarization reversal through the clamping of ferrimagnetic and ferroelectric domain walls. This behavior can be potentially used as a magnetically rewritable ferroelectric memory and an electrically rewritable magnetic memory.
We have investigated magnetic-field (H [100]) effect on a spin-frustrated tetragonally distorted spinel Mn 3 O 4 by measurements of magnetization, dielectric constant, and strain as well as synchrotron x-ray and neutron diffraction. In two low-temperature phases below 40 K, long-wavelength lattice modulations coupled with magnetic order have been confirmed, revealing spin-lattice coupling caused by the exchange striction in the geometrically frustrated Mn 3+ spin moments on the distorted pyrochlore lattice. A magnetic-field-induced phase transition has been found at low temperatures, which involves an abrupt change in both structural and magnetic configurations. The magnetostructural phase transition by the application of a magnetic field H [100] is discussed in terms of interplay among spin, orbital, and lattice degrees of freedom.
The relation between the orientation of the magnetic field and the flopped ferroelectric polarization has been investigated for multiferroic MnWO4. The ferroelectric single-domain state is retained across the polarization flop process when the direction of the applied magnetic field slightly deviates from the b axis within the ab plane. Furthermore, the electric polarization in the high-field P parallela phase is reversed when the P parallelb-to-P parallela transition takes place while decreasing and increasing the magnetic fields oppositely canted from the b axis. These results indicate that the symmetry breaking induced by a canted magnetic field determines the direction of the polarization flop, which corresponds to the direction of the vector spin chirality. The stability of the magnetoelectric domain walls in a canted magnetic field play a key role in the directional control of the electric polarization flop phenomenon.
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