Controlling ion transport in nanofluidics is fundamental to water purification, bio-sensing, energy storage, energy conversion, and numerous other applications. For any of these, it is essential to design nanofluidic channels that are stable in the liquid phase and enable specific ions to pass. A human neuron is one such system, where electrical signals are transmitted by cation transport for high-speed communication related to neuromorphic computing. Here, we present a concept of neuro-inspired energy harvesting that uses confined van der Waals crystal and demonstrate a method to maximise the ion diffusion flux to generate an electromotive force. The confined nanochannel is robust in liquids as in neuron cells, enabling steady-state ion diffusion for hundred of hours and exhibiting ion selectivity of 95.8%, energy conversion efficiency of 41.4%, and power density of 5.26 W/m2. This fundamental understanding and rational design strategy can enable previously unrealisable applications of passive-type large-scale power generation.
Lithium metal is considered one of the most promising anode materials for application in next-generation batteries. However, despite decades of research, practical application of lithium metal batteries has not yet been achieved because the fundamental interfacial mechanism of lithium dendrite growth is not yet fully understood. In this study, a series of reactive molecular dynamics (MD) simulations was performed to investigate the electrochemical dynamic reactions at the electrode/electrolyte interface. It allows quantitative characterization of morphological phenomena and real-time interfacial visualization of the dynamic growth of dead lithium and dendrites during repeated charging. This computational protocol was utilized to investigate the dendrite mitigation mechanism when an electrolyte additive (hydrogen fluoride) is dissolved in an organic ethylene carbonate (EC) electrolyte solvent. It was confirmed that beneficial decomposition reactions between electrolyte components form a protective film on the anode surface, suppressing large interphase volume changes and unnecessary degradation reactions.
Wetting Na metal on the solid electrolyte of a liquid
Na battery
determines the operating temperature and performance of the battery.
At low temperatures below 200 °C, liquid Na wets poorly on a
solid electrolyte near its melting temperature (T
m = 98 °C), limiting its suitability for use in low-temperature
batteries used for large-scale energy-storage systems. Herein, we
propose the use of sparked reduced graphene oxide (rGO) that can improve
the Na wetting in sodium-beta alumina batteries (NBBs), allowing operation
at lower temperatures. Experimental and computational studies indicated
rGO layers with nanogaps exhibited complete liquid Na wetting regardless
of the surface energy between the liquid Na and the graphene oxide,
which originated from the capillary force in the gap. Employing sparked
rGO significantly enhanced the cell performance at 175 °C; the
cell retained almost 100% Coulombic efficiency after the initial cycle,
which is a substantial improvement over cells without sparked rGO.
These results suggest that coating sparked rGO is a promising but
simple strategy for the development of low-temperature NBBs.
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