Landfilling is widely adopted as one of the most economical processes for solid waste disposal. At the same time, landfill leachate is also a great environmental concern owing to its complex composition and high concentrations of contaminants. This research investigated electrocoagulation and fiber filtration for the treatment of landfill leachate. Besides electrical current (i.e., current density) and reaction time, pH played a very important role in arsenic and phosphorus removal by electrocoagulation. The combination of electrocoagulation with fiber filtration achieved a 94% chemical oxygen demand (COD), 87% arsenic, 96% iron, and 86% phosphorus removal. During electrocoagulation, the micro-particles that could not be settled by gravity were removed by the first stage of fiber filtration. Organic contaminants in the leachate were further removed by biodegradation in the second stage of fiber biofiltration.

Nowadays, use of constructed wetlands for wastewater treatment especially in rural areas has become increasingly preferable. The most important reason behind this fact is its relatively low investment cost over other treatment options depending on economical conditions of the country. Nonetheless, due to lower operational costs of constructed wetlands than other conventional wastewater treatment systems, investment costs could be regarded secondary as of importance. Investment costs could show differences even at regional scale in a country. Choosing a constructed wetland system among “Subsurface Horizontal Flow”, “Subsurface Vertical Flow” or “Free Water Surface Flow”; or designing a hybrid system using concurrent systems plays important role when defining costs of the constructed wetland systems. Due to increasing interest for constructed wetlands since 2003, so many constructed wetland systems have been built in rural parts of Turkey and most of these systems have been designed as horizontal subsurface flow constructed wetland system. As a fact, the cost of horizontal subsurface flow constructed wetlands is comparatively higher than other wetland systems. When different applications in the world are examined, it is observed that mostly horizontal subsurface flow constructed wetland systems are preferred in rural areas. According to the studies within the extent of this work, different constructed wetland types which are built in different regions of Turkey and their expected and realized costs are analyzed and compared with other countries. Moreover, operational costs have been calculated. Consequently, a work to be taken as reference for further scientific studies has been prepared with presented wetland analyses which could be used by especially decision makers and researchers.

The electrokinetic technique is an emerging technology presently tested in situ to remove dissolved heavy metals from contaminated groundwater. There is a growing interest for using this system to cleanse clayey soil contaminated by toxic metallic ions. Currently, there are very few available non-destructive treatment methods that could be successfully applied in situ on low permeable type of soil matrix. The main objective of presented study was to validate and possibly enhance the overall efficiency of decontamination by the electrokinetic technique of the low permeable soil polluted by the arsenic in combination with chromium and copper ions. The chosen mixture of ions was imitating leak of pesticide well known as chromate copper arsenate (CCA). The chosen technique is showing a big promise to be used in the future as a portable, easy to install and run on sites with spills or leaks hard to reach otherwise; such as in the dense populated and urbanized areas. Laboratory electrokinetic experiments were designed to understand and possibly manipulate main mechanisms involved during forced migration of ions. All tests were conducted on artificially contaminated kaolinite (low permeable clay soil). Electrokinetic migration was inducted by the low voltage dc current applied through soil column. Series of experiments were designed to assess the efficiency of arsenic-chromium-copper remediation by applying (1) only dc current; and (2) by altering the soil environment. Obtained results showed that arsenic could be successfully removed from the soil in one day (25 hours) span. It was significant time reduction, very important during emergency response. Mass recovered at the end of each test depended on initial condition of soil and type of flushing solution. The best results were obtained, when soil was flushed with either NaOH or NaOCl (total removal efficiency 74.4% and 78.1%, respectively). Direct analysis of remained arsenic in soil after these tests confirmed substantial drop of the initial mass of arsenic in soil profile from 51.54 mg to 10.62 mg (NaOH) and 5.68 mg (NaOCl) after 25 hours of treatment.