xBiFeO3-(1-x)Ba5TbTi3V7O30 (xBFO-BTTV) ceramic composites with different x
values were prepared by high temperature solid state reaction technique and
sintering at 1073K. The formation of composite structure consisting of BFO
and BTTV phases was confirmed by XRD study. Surface morphology was studied
by scanning electron microscope (SEM) and shows that structure with high
density was obtained in the composite 0.3BFOBTTV whereas the average grain
size increases by increasing x, i.e. by increasing amount of BiFeO3 in the
system. Magnetic measurements were done in a wide temperature range, i.e.
from 10 to 350K, by vibrating sample magnetometer (VSM) and showed that the
magnetization changes by changing the value of x in the composite. BiFeO3 is
antiferromagnetic in nature with weak ferromagnetism. Addition of
Ba5TbTi3V7O30 enhances magnetic properties of the composite and maximal
coercivity and remnant magnetization are obtained in the composite
0.7BFO-BTTV.
Bismuth Ferrite (BiFeO3) is a single phase Fe- based multiferroic having Perovskite structure. It shows both ferroelectric and ferromagnetism simultaneously in the single material. But the magnetic order is very low due to complex antiferromagnetic order yielding small remnant magnetization. However, Magnetic property could be improved if BiFeO3 mixed with Ba5PrTi3V7O30 having TB-structure. Solid Solution (1-x)Ba5PrTi3V7O30-xBiFeO3 is prepared by using Solid State Reaction technique for different values of x. Pellets are calcined at 750 then sintered at 800 . Basic Crystal qualities and formation of single phase compound is confirmed by the XRD (X-Ray Diffractogram). The crystal structure is more or less constant i.e. Orthorhombic. However, further increase in x changes the crystal structure. For x= 0.7 the system is Rhombohedral in structure. Grain morphology is being analysed by Scanning Electron Microscope (SEM: JOEL-IT300).Surface morphology shows that average grain size range from around 0.75 µm to 2.10 µm. Average grain size is maximum for x = 0.3 and minimum for x=0 (i.e. pure ferroelectric material). Magnetic measurement is done at a wide low temperature range (10-350K) by Physical Property Measurement System (PPMS: Quantum Design, San Diego, USA) Vibrating Sample Magnetometer (VSM). Hysteresis (M-H) loops are measured at room temperature (300K).It shows that the magnetization changes when the value of x changes. Remanence is maximum for x=0.3 and Coercivity is maximum for x=0.7. The material could be suitable to fabricate non volatile magnetic storage memory device.
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