Let (X , d, µ) be a metric measure space satisfying both the geometrically doubling and the upper doubling conditions. Let ρ ∈ (1, ∞), 0 < p 1 q ∞, p = q, γ ∈ [1, ∞) and ǫ ∈ (0, ∞). In this article, the authors introduce the atomic Hardy space H p, q, γ atb, ρ (µ) and the molecular Hardy space H p, q, γ, ǫ mb, ρ (µ) via the discrete coefficient K (ρ), p B, S , and prove that the Calderón-Zygmund operator is bounded fromThe authors also introduce the ρ-weakly doubling condition, with ρ ∈ (1, ∞), of the measure µ and construct a non-doubling measure µ satisfying this condition. If µ is ρ-weakly doubling, the authors further introduce the Campanato space E α, q ρ, η, γ (µ) and show that E