Compared with other enhanced oil recovery (EOR) techniques like gas flooding, chemical flooding, and thermal production, the prominent advantages of microbial enhanced oil recovery (MEOR) include environment-friendliness and lowest cost. Recent progress of MEOR in laboratory studies and microbial flooding recovery (MFR) field tests in China are reviewed. High biotechnology is being used to investigate MFR mechanisms on the molecular level. Emulsification and wettability alternation due to microbial effects are the main interests at present. Application of a high-resolution mass spectrum (HRMS) on MEOR mechanism has revealed the change of polar compound structures before and after oil degradation by the microbial on the molecular level. MEOR could be divided into indigenous microorganism and exogenous microorganism flooding. The key of exogenous microorganism flooding was to develop effective production strains, and difficulty lies in the compatibility of the microorganism, performance degradation, and high cost. Indigenous microorganism flooding has good adaptation but no follow-up process on production strain development; thus, it represents the main development direction of MEOR in China. More than 4600 wells have been conducted for MEOR field tests in China, and about 500 wells are involved in MFR. 47 MFR field tests have been carried out in China, and 12 field tests are conducted in Daqing Oilfield. MFR field test’s incremental oil recovery is as high as 4.95% OOIP, with a typical slug size less than 0.1 PV. The input-output ratio can be 1 : 6. All field tests have shown positive results in oil production increase and water cut reduction. MEOR screening criteria for reservoirs in China need to be improved. Reservoir fluid, temperature, and salinity were the most important three parameters. Microbial flooding technology is mature in reservoirs with temperature lower than 80°C, salinity less than 100,000 ppm, and permeability above 5 mD. MFR in China is very close to commercial application, while MFR as quaternary recovery like those in post-polymer flooding reservoirs needs further study.
Compared with other EOR technique like gas flooding, chemical flooding, and thermal production in heavy oil, the prominent advantages MEOR has environment-friendliness and lowest cost. MEOR has various applications not only in sandstone but also carbonate reservoirs, light oil reservoirs as well as heavy oil reservoirs. This paper mainly reviewed progress in laboratory studies and MEOR field tests including six big successful field tests in China. Present focus on MEOR has been changed from qualitative analysis to quantitative characterization, and high-tech like 16S rDNA and advanced method has being tried to investigate its mechanism on molecular level. The mechanism of microbial effects on making oil emulsification and wettability alternation was the main interest of recent study. Application of high resolution mass spectrum (HRMS) on MEOR mechanism has revealed the change of polar compound structures before and after oil degradation by the microbial on molecular level. MEOR could be divided into indigenous microorganism and exogenous microorganism flooding. The key of exogenous microorganism flooding, was to develop effective production strains, and difficulty lies in the compatibility of microorganism, performance degradation and high cost. Indigenous microorganism flooding, has good adaptation but no follow up process on production strains development, thus it represents the main direction of MEOR. China has some of the most complex and diversified reservoirs and was notable for the scale of MEOR field tests since there has been six big MEOR field tests since 1998 after many precious small-cale tests. All field tests have shown positive results in incremental oil and water cut reduction. The combination of indigenous microorganism and exogenous microorganism flooding was adopted because of the cost and difficulty of exogenous microorganism flooding. MEOR screening criteria for reservoirs has been improved. The parameters include temperature, salinity, oil viscosity, permeability, porosity, wax content, water cut, and microorganism concentration in which production fluid, temperature, and salinity were the most important three parameters. MEOR was suitable in reservoirs of which temperature lower than 80°C, salinity less than 100,000 ppm, and permeability above 50 mD. MEOR experience and study in reservoirs of 120°C, salinity more than 350,000ppm and permeability of 10 mD has expanded the reservoirs range suitable to carry out MEOR.
This paper provides field scale EOR survey in China which is in line with biennial worldwide EOR survey published by Oil& Gas Journal (OGJ). The EOR progress in China is not available due to language difference and other reasons in OGJ EOR survey. From 2018, EOR survey in China will be published biennially. The first part of this survey mainly focuses on basic information. Chemical flooding, unconventional heavy oil, green recovery and natural gas recovery progress in China will be surveyed and discussed in detail in the other four parts elsewhere. The EOR projects including field tests and field applications in China are summarized in the same pattern as OGJ to the largest extent for better readership outside China. Most data is collected from published journal papers and reports. Different from other countries, there are only four major oil companies in China: CNPC, SINOPEC, CNOOC and Yanchang Oil. The 28 branch companies of these four companies are both operator and owners. Oil and gas production from CNOOC is all offshore. CNPC is the largest oil company in China and its oil production in 2016 accounts for 54% oil production in China. EOR survey in China includes chemical flooding (polymer, SP and ASP flooding, gas flooding (CO2, nitrogen and air), thermal production, MEOR, and foam flooding. EOR production in China in 2016 accounts for 18% total oil production, while chemical EOR accounts for 10 %. Up to present, there has been more than 34 ASP flooding projects in China, most in Daqing. The total ASP oil production in 2016 is 407 million tons. More than 30 SP flooding projects have been carried out, with incremental oil recovery factor of 7%-18% OOIP. More than 170 polymer flooding projects have been carried out. Polymer flooding has been used widely in Daqing, Shengli, Xinjiang, Liaohe, He'nan and Bohai. The incremental oil recovery from polymer flooding and ASP flooding is 7%-15% and 18%-30% OOIP respectively. Gas flooding in China is not as successful as chemical EOR. Polymer flooding production in the largest offshore oilfield in CNOOC accounts for 25% total oil production in 2016. While EOR production in China accounts for 15%-18% in recent years, however, the world EOR oil production only accounts for about 3.3% total oil production. EOR is greatly affected by oil price, as indicated from 26 years EOR content change in America. It is the first time that detailed EOR survey in China in line with worldwide EOR survey in OGJ is given. The EOR survey in China provides valuable and helpful information for engineers and researchers in oil and gas industry.
In reviewing Chinese shale gas reserves and national policies regarding shale gas exploitation, shale gas will be of critical importance in providing clean natural gas to China. However, compared to those in the United States, the cost of shale gas extraction and the complex problems encountered in more complex and deep drilling in China are key technologies that need to be overcome. Shale wellbore wall instability is a complex problem that often occurs during drilling. During the process of drilling in shale, the complex stress and fluid-structure interactions result in the wall rock generating a strong hydration diffusion and swelling effect, which alters the stress distribution in the rock wall and deteriorates the mechanical parameters of the rock. This results in instability damage of the shale wellbore wall. In this study, the stratigraphic stress characteristics of the Fuling Shale Gas Field were initially predicted, and the shale sample phase composition and development of bedding and microcracks were analyzed using X-ray diffraction and scanning electronic microscopy. The main driving potential difference function between the drilling fluid and shale was analyzed, and a radial adsorption diffusion model of the shale plane was established. Through a laboratory study, the space time change law of the water diffusion of the shale rock was assessed as well as the rock damage evolutionary law of the elastic modulus and compressive strength with water content. Then, combined with the shale hydration stress and strength deformation theory, a damage evolutionary equation for shale with water was derived, and the shale damage evolutionary limit equation and the method of determining the collapse cycle were established. Finally, the method was applied to the Fuling Shale Gas Field, the largest shale gas field in China, and a shale wellbore collapse cycle of approximately seven days in the field was obtained. The severity of economic loss resulting from wellbore wall instability was also determined. This study provides insight and guidance for reducing the costs of shale gas reservoir well drilling and efficient development.
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