Water pollution caused by chemical reagent leaking, industrial wastewater discharging, and crude oil spills has raised global concerns on environmental sustainability, calling for high-performance absorbent materials for effective treatments. However, low-cost materials capable of effectively separating oils and organic solvents from water with a high adsorption capacity and good recyclability are rare on the market. Here, a cost-effective method is reported to fabricate high-performance graphene modified absorbents through the facile thermal reduction of graphene oxide on the skeletons of melamine foam. By integrating the high porosity, superior elasticity, and mechanical stability of raw sponge with the chemical stability and hydrophobicity of graphene sheets, the as-fabricated graphene foam not only possesses a rough and superhydrophobic surface, but also exhibits an excellent adsorption performance and extraordinary recyclability for various oils and organic solvents. It is worth mentioning that the superhydrophobic surface also endows the graphene foam with an excellent efficiency for oil/water separation. More importantly, the cost-effective fabrication method without involving expensive raw materials and sophisticated equipment permits a scale-up of the graphene foam for pollution disposal. All these features make the graphene foam an ideal candidate for removal and collection of oils and organic solvents from water.

One of the most pervasive environmental issues is water contaminated with oil or organic solvents; this global challenge calls for emerging materials that could effectively separate oil or organic solvents from water. Here, such a material is presented by integrating 3D porous graphene foam (GF) with a smart pH‐responsive surface, showing switchable superoleophilic and superoleophobic properties in response to the medium pH. The key chemistry applied in this study is to modify the 3D porous GF with an amphiphilic copolymer containing a block of poly(2‐vinylpyridine) and polyhexadecyl acrylate (P2VP‐b‐PHA), resulting in a smart GF (ss‐GF) with an either superoleophilic or superoleophobic surface at different medium pH. The as‐designed ss‐GF can effectively absorb oil or organic solvents from the aqueous media by using its superoleophilic surface at pH of 7.0, and it can also completely release the adsorbates when the pH is switched to 3.0 (and the surface of ss‐GF is therefore shifted to superoleophobic); with a continuous operation of many cycles (e.g., >10). Furthermore, the as‐designed ss‐GF shows superior absorption capacity for oil and organic solvent, with a high capacity of ≈196 times of the weight relative to that of the pristine ss‐GF. The present work suggests encouraging applications of the ss‐GF to water–oil and water–organic solvent separation.

Water pollution, a worldwide issue for the human society, has raised global concerns on environmental sustainability, calling for high-performance materials for effective treatments. Since the traditional techniques have inherent limitations in treatment speed and efficiency, nanotechnology is subsequently used as an environmental technology to remove pollutants through a rapid adsorption and degradation process. Therefore, here, various adsorbent and photodegradation composite materials leading to effective water remediation are summarized and predicted. Notably, recent advances in simultaneous adsorption and photodegradation micro-nanocomposites are outlined. Such materials can not only completely adsorb and remove contaminants, but the micro-nanocomposites can also be directly reused without further treatment. Finally, the future development of this unique system is discussed.

We decorated per-6-thio-β-cyclodextrin protected gold nanoclusters on TiO2 nanoparticles to improve photocatalytic activity by inhibiting electron–hole pair recombination and absorbing organic targets via host–guest interactions.