In this work, a high gain broadband photoconductor based on a wide bandgap amorphous gallium oxide film was reported. Meanwhile, a novel short-time heating method was demonstrated to effectively suppress the PPC effect.
Cesium‐lead‐halide perovskite quantum dots (PQDs), which have superior optical and electronic properties, are regarded as excellent materials for various optoelectronic devices. However, their unstable nature greatly hinders their practical application. Herein, a simple hydrolysis encapsulation method is developed to embed PQDs into mesoporous polystyrene microspheres (MPMs) followed by a silica shell covering process, which generates luminescent PQDs/MPMs@SiO2 hybrid microspheres with significantly enhanced stability. The obtained CsPbBr3‐PQDs/MPMs@SiO2 hybrid microspheres show a high photoluminescence quantum yield of 84%. More importantly, the MPMs@silica protective shells effectively cut off direct contact between outer erosive species and the inner embedded PQDs and modify the hybrid microspheres with ultralong alkyl chains for improved resistance to solvents and heat. Hence, these CsPbBr3‐PQDs/MPMs@SiO2 hybrid microspheres exhibit good chemical/physical stabilities, even when exposed to harsh environments, such as deionized water, isopropanol, acid/alkali solution, anion‐exchange reactions, and heating. Particularly, the water stability, which produced the remaining ≈48% proportion of the initial fluorescence intensity after a quite long aqueous storage period of 30 d, is the best reported among the stability‐related studies of PQDs. Meanwhile, white light‐emitting diodes (LEDs) are achieved by mixing green CsPbBr3‐PQDs/MPMs@SiO2 microspheres with red commercial phosphors on a blue chip. High power efficiency of 81 lm W−1 and good electroluminescence stability are obtained.
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