Uniform nanodonuts: Stable toroidal micelles that have a highly uniform size and shape spontaneously self-assemble from a selective THF/ethanol solvent mixture (see 3D AFM image). The donut-shaped micelles can be used as a template to grow gold nanoparticles, which form along the ring surface.

SUMMARYTool‐rock interaction processes can be classified as indentation or cutting depending on the direction of motion of the tool with respect to the rock surface. The modes of failure induced in the rock by an indenting or a cutting tool can be ductile and/or brittle. The ductile mode is associated with the development of a damage zone, whereas the brittle mode involves the growth of macrocracks. This is the first part of a series of two papers concerned with an analysis of the cutting and the indentation processes based on using the discrete element method. In this paper, numerical simulations of the cutting process are conducted to reproduce the transition from a ductile to a brittle failure mode with increasing depth of cut, which is observed in experiments. The numerical results provide evidence that the critical depth of cut d *  controlling the failure mode transition is related to the characteristic length ℓ = (KIc ∕ σc)2 with KIc denoting the material toughness and σc its unconfined compressive strength. The nature of frictional contact between the cutter face and the rock in the ductile failure mode is also examined. It is shown that the inclination of the total cutting force is controlled by a multi‐directional flow mechanism ahead of the cutter that is related to the formation of a wedge of failed material, intermittently adhering to the cutter. As a result, the inclination of the total cutting force varies with the rake angle of the cutter and cannot be considered an intrinsic measure of the interfacial friction between the cutter and the rock. Copyright © 2012 John Wiley & Sons, Ltd.

Microwave-assisted polymerization has been utilized to synthesize amphiphilic poly(2-ethyl-2-oxazoline-block-2-"soy alkyl"-2-oxazoline) diblock copolymers (PEtOx-PSoyOx). The amphiphilic block copolymers have been used to prepare aqueous spherical micelles consisting of a PEtOx corona and a PSoyOx core, which have been further cross-linked by UV irradiation. The morphology of these cross-linked micelles has been shown to reversibly change from spheres to short rods referred to as rice grains whenever the micelles were transferred from water into acetone, a nonselective solvent for the constituent blocks. This morphological transition has been attributed to the swelling of the slightly cross-linked PSoyOx core.

We report on the first successful example of the preparation of triblock copolymers via a cationic ring-opening polymerization procedure. A library of 30 triblock copolymers was prepared from 2-methyl-, 2-ethyl-, 2-nonyl-, and 2-phenyl-2-oxazoline in a single-mode microwave reactor. The polymers exhibited narrow molecular weight distributions and showed only minor deviations from the targeted monomer ratio of 33:33:33. The glass-transition temperature of the triblock copolymers spanned the range from 50 to 100 °C depending on the incorporated monomers. The micellization behavior was investigated for some amphiphilic triblock copoly(2-oxazoline)s containing two hydrophilic and one hydrophobic blocks. The size of the micelles was larger when the hydrophobic block is located at one end of the triblock copoly(2-oxazoline)s, as measured by atomic force microscopy and dynamic light scattering.