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The densities of ternary systems ([Emim][Cl]+ LiCl + H 2 O), ([Emim][Cl] + LiBr + H 2 O), and ([Emim][Cl]+ LiNO 3 + H 2 O) and also binary system ([Emim][Cl] + H 2 O) were measured at T = (298.15 to 318.15) K using a vibrating U-tube densimeter. On the basis of experimental density data, the apparent molar volumes, V φ , were computed. The values of apparent molar volumes for binary system were correlated to Redlich−Meyer and Pitzer equations and for ternary systems were correlated to Redlich−Meyer equation and apparent molar volumes at infinite dilution, V φ 0 , are also calculated. Our results showed a negative transfer volume of [EmimCl] from water to the aqueous LiCl, LiBr, and LiNO 3 solutions, which decrease by enhancing the salt mass fraction. The solute−solvent interactions and structure making or breaking ability of [Emim][Cl] have been discussed in details. The results of second derivative of limiting apparent molar volumes showed that the studied ionic liquid in this work acts as a structure maker.