In order to improve the properties of unsaturated polyesters, this study discusses the possibilities of developing a natural waste, date palm leaf fiber DPLF, produced in the northern Algerian Sahara, associated with the polymer matrix of a thermosetting polyester resin UP. For this purpose, composite plates containing virgin fiber at rates of 6 and 10% were treated with an alkaline solution of 6% NaOH on the one hand, and a silane compound on the other. In this research, a mechanical study of strength and elongation at break was carried out. In addition, morphological behavior was followed by SEM scanning electron microscopy. ATG thermogravimetric analysis and energy flow were monitored by DSC differential scanning calorimetry. Also, a study of the water absorption capacity has been conducted. In addition, a dynamic mechanical analysis DMA was carried out. The findings of this study show that there is a favorable mechanical behavior for the composites containing the 6% and 10% DPLF fiber, with alkaline NaOH and Silane treatment. They also show that the chemical treatment with alkaline solution and silane gives composites certain thermal stability compared to those with untreated fiber. Findings also explore that the absorption of water by the various composites shows that the chemical treatment promotes some intermolecular associations with water. Findings also show that the storage modulus (E') increases when the composite contains 10% DPLF, treated and untreated, and the maximum value of the tangent moves towards the high temperature for the treated and untreated fiber composite.

In this study, polymer-hybrid natural fibers composites were prepared using unsaturated polyester resin (UPR) as the matrix and a filler using date palm leaf fiber (DPLF) and orange peel fiber (OPF). The effect of DPLF and OPF on mechanical behavior (tensile strength and elongation at break), moisture absorption, UPR gel time (tgel) and peak exothermic temperature (Tpeak) were determined. The composites of UPR reinforced with DPLF and OPF were processed by hand lay-up technique. The UPR weight fraction was maintained at 90%, and DPLF/OPF proportions varied so that the percentage of natural fiber was 10 wt%. Seven (07) composites were prepared (C1, C2, C3, C4, C5, C6 and C7) with different DPLF:OPF ratios (0:0, 1:0, 0.75:0.25, 0.5:0.5, 0.33:0.67, 0.25:0.75, 0:1) respectively in order to screen the possible interactions. DPLF were surface modified using 6% Alkali treatment, OPF were used without surface modification. Unlike DPLF, OPF showed considerable increase of UPR tgel and Tpeak which act as natural inhibitor. Tensile strength and fracture strength were also impacted negatively and positively depending on the different fiber proportions. Absorption tests showed a decrease in the composites hydrophobicity which increases significantly with higher DPLF proportions.