Antigorite dehydration is well known as a key process at convergent boundaries for the genesis of mantle wedge partial melting and intermediate‐depth earthquakes. However, the crystallographic preferred orientations (CPOs) of prograde minerals from antigorite dehydration and their effects on the seismic anisotropy of subducting slabs remain ambiguous and controversial. Here we report antigorite dehydration experiments on a foliated serpentinized peridotite at pressures of 0.3–6 GPa and temperatures of 700–900°C. Our results show that olivine CPO evolves from a fiber‐[100] type in fine grains to a type‐C like in coarse grains. We propose that the fiber‐[100] olivine CPO is developed by topotactic growth during incipient hydrostatic dehydration, while the orthorhombic type‐C like olivine CPO is developed by anisotropic growth resulting from an anisotropic fluid flow during later dehydration. The type‐C like olivine CPO in the antigorite‐rich layers after antigorite dehydration could contribute to the trench parallel fast shear wave seismic anisotropy at convergent plate boundaries.
The bulk rock composition of granitoids reflects the composition of their source and the conditions of partial melting, which are functions of the geodynamic setting in which they formed. Granitoids in active continental margins (continental arcs) are dominated by calc-alkaline rocks with subordinate alkaline compositions, although how these different magma compositions formed is not well understood. Neoproterozoic magmatic rocks are widely distributed along the western margin of the Yangtze Block in South China to form the >1000-km long Panxi continental arc system, which is dominated by granitoids with minor mafic–ultramafic and intermediate plutons. The granitoids are subdivided into sodic and potassic variants that occur as belts along the western and eastern sides of the continental arc, respectively. Sodic granitoids from the western part consist of tonalite, granodiorite, and monzogranite with crystallisation ages ranging from 870 Ma to 740 Ma. They have low K2O/Na2O ratios (0.1–1.0) and high Na2O contents (3.5–6.7 wt%), high but variable SiO2 (61–75 wt%) concentrations, and negative to positive whole-rock εNd(t) values (−1.7 to +2.9). Zircon grains from the sodic granitoids have εHf(t) values ranging from +0.3 to +9.6 and δ18O from 3.90‰ to 7.71‰. The potassic granitoids from the eastern side consist of monzogranite and syenogranite with crystallisation ages from 820 Ma to 790 Ma. They have high K2O/Na2O ratios (0.6–2.2), K2O (2.6–6.0 wt%) and SiO2 contents (69–78 wt%), but whole-rock εNd(t) (−0.9 to +2.9) and zircon εHf(t) (+1.8 to +12.9), and δ18O values (2.98‰ to 6.41‰) similar to those of the sodic granitoids. The isotopic compositions of both the sodic and potassic granitoids are similar to those of spatially- and temporally-related mantle-derived (mafic to ultramafic) rocks, and are considered to have been derived from juvenile oceanic crust. Phase equilibrium modelling shows that the H2O content of the granitoid source rocks played a key role in their petrogenesis, both in lowering solidus temperatures and in controlling the compositions of the derived partial melts. Our results indicate that calc-alkaline sodic granitoids can be formed by water-fluxed melting of juvenile mafic crust at 750–900 °C and 9–12 kbar in which the required H2O was derived from the dewatering of underplating mafic arc magmas. By contrast, the potassic granitoids were generated by fluid-absent (H2O-undersaturated) partial melting of a similar juvenile mafic source at 725–900 °C and 6–9 kbar. We conclude that the sodic granitoids were derived from partial melting of subducting mafic crust, whereas the potassic granitoids were likely generated in a back-arc setting induced by upwelling of asthenospheric mantle.
Summary Conglomerate is characterized by a multiscale grain stacking structure and various pore size distribution modes (PSDMs), significantly affecting multiphase fluid movement and transport in porous media. The multimodal structure and complicated PSDM are related to grain size distribution. However, the relationship between grain size distribution and pore structure characteristics remains unclear, which makes it hard to investigate using natural rocks affected by a single factor. Herein, a newly developed full-pore-scale artificial rock approach was used in this work to provide the ideal samples for experimental research. A bimodal distribution model was adopted to characterize the grain size distribution features quantitatively. Furthermore, the relationship between lithofacies, permeability, and PSDM was analyzed. The results demonstrate that grain size distribution includes coarse grain distribution (CGD) and fine grain distribution (FGD). As the average value of FGD increases, the permeability of conglomerate and sandstone have different decreasing trends. The increases in the grain size difference between CGD and FGD can decrease the most frequent and average pore radius, while the PSDM of conglomerate transforms from a steep peak shape to a hill shape. Furthermore, PSDM relates to permeability and lithofacies in an alluvial fan environment. The maximum permeability of sandstone with PSDM of hill shape is about 40 md while that of conglomerate is about 70 md. The grain and pore size distribution of artificial rocks is highly similar to that of natural rocks compared with natural rocks within the alluvial fan of Karamay conglomerate reservoirs. The findings are significant for robust determination in reservoir evaluation and development.
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