As an important air pollutant, volatile organic compounds (VOCs) pose a serious threat to the ecological environment and human health. To achieve energy saving, carbon reduction, and safe and efficient degradation of VOCs, ambient temperature catalytic oxidation has become a hot topic for researchers. Firstly, this review systematically summarizes recent progress on the catalytic oxidation of VOCs with different types. Secondly, based on nanoparticle catalysts, cluster catalysts, and single-atom catalysts, we discuss the influence of structural regulation, such as adjustment of size and configuration, metal doping, defect engineering, and acid/base modification, on the structure–activity relationship in the process of catalytic oxidation at ambient temperature. Then, the effects of process conditions, such as initial concentration, space velocity, oxidation atmosphere, and humidity adjustment on catalytic activity, are summarized. It is further found that nanoparticle catalysts are most commonly used in ambient temperature catalytic oxidation. Additionally, ambient temperature catalytic oxidation is mainly applied in the removal of easily degradable pollutants, and focuses on ambient temperature catalytic ozonation. The activity, selectivity, and stability of catalysts need to be improved. Finally, according to the existing problems and limitations in the application of ambient temperature catalytic oxidation technology, new prospects and challenges are proposed.

Desertification, one of the world’s most pressing serious environmental problems, poses a serious threat to human survival as well as to social, economic, and political development. Nevertheless, the development of environmentally friendly sand-fixing materials is still a tremendous challenge for preventing desertification. This study developed a bio-based attapulgite copolymer (BAC) by grafting copolymerization of attapulgite, starch, sulfomethyl lignin, and biological mycelia. Water retention, anti-water erosion, and anti-wind erosion tests were conducted to assess the application performance of the BAC. Scanning electron microscopy (SEM) was then employed to determine the morphology of the attapulgite and attapulgite graft copolymer sand-fixing material (CSF). The intermolecular interactions in CSF were revealed using Fourier transform infrared spectrum (FT-IR). The role of sand-fixing materials on soil physicochemical properties and seed germination was then discussed based on the germination rate experiments, and 16S rDNA sequencing technology was used to analyze the differences in microbial communities in each sample group. The results demonstrated that the BAC not only has superior application properties and significantly increased seed germination (95%), but also promotes soil development by regulating the structure of the soil microbial community. This work provides novel insights into the design of sand-fixing material for preventing desertification while improving soil fertility.

Forward osmosis (FO) membranes have the advantages of low energy consumption, high water recovery rate, and low membrane pollution trend, and they have been widely studied in many fields. However, the internal concentration polarization (ICP) caused by the accumulation of solutes in the porous support layer will reduce permeation efficiency, which is currently unavoidable. In this paper, we doped Graphene oxide (GO) nanoparticles (50~150 nm) to a polyamide (PA) active layer and/or polysulfone (PSF) support layer, investigating the influence of GO on the morphology and properties of thin-film composite forward osmosis (TFC-FO) membranes. The results show that under the optimal doping amount, doping GO to the PA active layer and PSF support layer, respectively, is conducive to the formation of dense and uniform nano-scale water channels perpendicular to the membrane surface possessing a high salt rejection rate and low reverse solute flux without sacrificing high water flux. Moreover, the water channels formed by doping GO to the active layer possess preferable properties, which significantly improves the salt rejection and water permeability of the membrane, with a salt rejection rate higher than 99% and a water flux of 54.85 L·m−2·h−1 while the pure PSF-PA membrane water flux is 12.94 L·m−2·h−1. GO-doping modification is promising for improving the performance and structure of TFC-FO membranes.

Constructed wetlands (CWs) are generally used for wastewater treatment and removing nitrogen and phosphorus. However, the treatment efficiency of CWs is limited due to the poor performance of various substrates. To find appropriate substrates of CWs for micro-polluted water treatment, zeolite, quartz sand, bio-ceramsite, porous filter, and palygorskite self-assembled composite material (PSM) were used as filtering media to treat slightly polluted water with the aid of autotrophic denitrifying bacteria. PSM exhibited the most remarkable nitrogen and phosphorus removal performance among these substrates. The average removal efficiencies of ammonia nitrogen, total nitrogen, and total phosphorus of PSM were 66.4%, 58.1%, and 85%, respectively. First-order continuous stirred-tank reactor (first-order-CSTR) and Monod continuous stirred-tank reactor (Monod-CSTR) models were established to investigate the kinetic behavior of denitrification nitrogen removal processes using different substrates. Monod-CSTR model was proven to be an accurate model that could simulate nitrate nitrogen removal performance in vertical flow constructed wetland (VFCWs). Moreover, PSM demonstrated significant pollutant removal capacity with the kinetics coefficient of 2.0021 g/m2 d. Hence, PSM can be considered as a promising new type of substrate for micro-polluted wastewater treatment, and Monod-CSTR model can be employed to simulate denitrification processes.

The greenhouse effect is one of the concerning environmental problems. Farmland soil is an important source of greenhouse gases (GHG), which is characterized by the wide range of ways to produce GHG, multiple influencing factors and complex regulatory measures. Therefore, reducing GHG emissions from farmland soil is a hot topic for relevant researchers. This review systematically expounds on the main pathways of soil CO2, CH4 and N2O; analyzes the effects of soil temperature, moisture, organic matter and pH on various GHG emissions from soil; and focuses on the microbial mechanisms of soil GHG emissions under soil remediation modes, such as biochar addition, organic fertilizer addition, straw return and microalgal biofertilizer application. Finally, the problems and environmental benefits of various soil remediation modes are discussed. This paper points out the important role of microalgae biofertilizer in the GHG emissions reduction in farmland soil, which provides theoretical support for realizing the goal of “carbon peaking and carbon neutrality” in agriculture.