Wheat bran is modified thermochemically through reaction with citric acid, as carboxyl groups bearing agent, according to a dry condition method at the elevated temperature. In this study, the main objectives are optimization the factors affecting on the pendant carboxylic acid groups of wheat bran–citrate, including concentration of citric acid solution (0–1.8 M), volume of citric acid solution (5.4–16.2 g), curing temperature (0–170 °C), curing time (0–90 min.), mixing method (solution mixing vs kneading) of reactants, and the catalyst effect (0–5, sodium phosphate dibasic dodecahydrate/citric acid molar ratio). The amount of pendant carboxylic acid groups is determined by simple acid-base titration. The obtained methylene blue adsorption data is well matched with the amount of pendant carboxylic acid groups in wheat bran–citrate and this amount increase with an increase in pendant carboxylic acid groups.

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This study reports the preparation of a novel type of support based on magnetically recyclable bentonite functionalized with divinylbenzene-polyvinyl pyridine (PVP-DVB) for Pd (II) nanocatalyst by a simple cost-effective method. Firstly, the conventional co-precipitation method synthesized Fe3O4 nanoparticles (NPs) onto bentonite sheets. Then the prepared magnetic support surface was functionalized by divinylbenzene-polyvinyl pyridine (PVP-DVB) to create a cross-linked polymer with a high coordination ability with palladium. Repeated nitrogen units in the PVP-DVB polymer chain increase the number of Pd bonds and thus lead to higher performance of the nanocatalyst. Finally, the palladium NPs were simultaneously synthesized and immobilized under mild conditions. The synthesized nanocatalyst was characterized by several methods such as scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, vibrating sample magnetometer, inductively coupled plasma mass spectrometry and thermogravimetric analysis. The efficiency of synthesized heterogeneous nanocatalyst was investigated in Suzuki–Miyaura cross-coupling reactions between a range of aryl halides (X = Cl, Br, I) with phenylboronic acid and in the reduction of 4-nitrophenol (4-NP). Moreover, the synthesized nanocatalyst could be easily recovered and reused several times with an efficiency greater than 90%.

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