We
developed a novel solar steam generator (SSG) with high solar
conversion efficiency and excellent salt resistance. A CO2 laser was used to convert the surface of basswood to graphitic carbon
layers (GCL), and various grid patterns of GCL were created on wood.
The low thermal conductivity of wood suppressed heat loss to bulk
water, and the presence of the grooves in the grid increased the evaporation
rate by increasing the surface area to absorb more sunlight. In addition,
the supply of bulk water through the grooves endowed the SSG with
salt resistance and self-regeneration properties. The salt resistance
was maintained in a 20-wt % NaCl solution for the duration of the
experiment (2 weeks), which indicates that the developed SSG can be
used in saline water for long-term operation.
A CO2 laser
was employed to create a rectangle (4 ×
2 mm2) of a conductive graphitic carbon layer (GCL) directly
on a cellulose substrate. By tilting the substrate while keeping the
laser power constant, the laser power density was gradually changed
while scanning in the direction of the long side of the rectangle,
due to deviation of the laser focus. As the laser beam defocus distance
increased, the laser intensity at the substrate decreased, and the
oxygen-to-carbon ratio (O/C) of the GCL increased. Upon exposing the
GCL substrate to water vapor, the hydrogen-containing groups (carboxyl
and hydroxyl groups) in the GCL were hydrolyzed, and a density gradient
of hydrogen ions was induced due to the preformed O/C gradient. The
resulting voltage and current outputs reached 0.23 V and 0.4 μA/cm2, respectively, at 70% relative humidity. Additionally, it
was demonstrated that the electricity obtained during breathing could
turn on a green light-emitting diode operating at an onset potential
of 2 V when an array of the GCLs was attached to a filter mask.
Ultrafast and reversible colorimetric responses to humidity changes are observed with disordered, nanoporous titania microspheres, optimized in speed and intensity with a monolayer coverage. The response times, defined by intracrystalline diffusion of water molecules, represent the fastest values for colorimetric humidity sensors.
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