A composite of high entropy ceramic B4(HfMo2TiTa)C and SiC was fabricated from refractory metallic carbides and B4C with superior mechanical properties.
In-situ processing of tungsten aluminide and tungsten reinforced aluminium matrix composites from elemental tungsten (W) and aluminium (Al) was investigated by thermal analysis and pulsed current processing (PCP). The formation mechanism of tungsten aluminides in 80 at.% Al-20 at.% W system was controlled by atomic diffusion. The particle size of W and Al in the starting powder mixture regulated the phase formation and microstructure. PCP of micron sized elemental Al and W resulted in formation of particulate reinforcements, W, Al4W and Al12W, dispersed in Al matrix. W particles were surrounded by a ~3 μm thick dual-layer structure of Al12W and Al4W. The hardness of Al matrix, containing Al12W reinforcements, was increased by 50% compared to pure Al, from 0.3 GPa to 0.45 GPa and W reinforcements showed a hardness of 4.35 GPa. On PCP of 80 at.% Al-20 at.% W mixture with particle size of W and Al ~70 nm, resulted in formation of Al4W as major phase along with small fractions of Al5W and unreacted W phase. This suggested strongly that the particle size of the starting elemental Al and W could be the controlling parameter in processing and tailoring of phase evolution, microstructure of particulate reinforced Al matrix composite.
Quaternary high-entropy ceramic (HEC) composite was synthesized from HfC, Mo2C, TaC, and TiC in pulsed current processing. A high-entropy solid solution that contained all principal elements along with a minor amount of a Ta-rich phase was observed in the microstructure. The high entropy phase and Ta-rich phase displayed a face-centered cubic (FCC) crystal structure with similar lattice parameters, suggesting that TaC acted as a solvent carbide during phase evolution. The addition of B4C to the quaternary carbide system induced the formation of two high-entropy solid solutions with different elemental compositions. With the increase in the number of principal elements, on the addition of B4C, the crystal structure of the HEC phase transformed from FCC to a hexagonal structure. The study on the effect of starting particle sizes on the phase composition and properties of the HEC composites showed that reducing the size of solute carbide components HfC, Mo2C, and TiC could effectively promote the interdiffusion process, resulting in a higher fraction of a hexagonal structured HEC phase in the material. On the other hand, tuning the particle size of solvent carbide, TaC, showed a negligible effect on the composition of the final product. However, reducing the TaC size from −325 mesh down to <1 µm resulted in an improvement of the nanohardness of the HEC composite from 21 GPa to 23 GPa. These findings suggested the possibility of forming a high-entropy ceramic phase despite the vast difference in the precursor crystal structures, provided a clearer understanding of the phase transformation process which could be applied for the designing of HEC materials.
Ultra-high temperature ceramic composites have been widely investigated due to their improved sinterability and superior mechanical properties compared to monolithic ceramics. In this work, high-entropy boron-carbide ceramic/SiC composites with different SiC content were synthesized from multicomponent carbides HfC, Mo2C, TaC, TiC, B4C, and SiC in spark plasma sintering (SPS) from 1600 °C to 2000 °C. It was found that the SiC addition tailors the phase formation and mechanical properties of the high-entropy ceramic (HEC) composites. The microhardness and fracture toughness of the HEC composites sintered at 2000 °C were improved from 20.3 GPa and 3.14 MPa·m1/2 to 26.9 GPa and 5.95 MPa·m1/2, with increasing SiC content from HEC-(SiC)0 (0 vol. %) to HEC-(SiC)3.0 (37 vol. %). The addition of SiC (37 vol. %) to the carbide precursors resulted in the formation of two high-entropy ceramic phases with two different crystal structures, face-centered cubic (FCC) structure, and hexagonal structure. The volume fraction ratio between the hexagonal and FCC high-entropy phases increased from 0.36 to 0.76 when SiC volume fraction was increased in the composites from HEC-(SiC)0 to HEC-(SiC)3.0, suggesting the stabilization of the hexagonal high-entropy phase over the FCC phase with SiC addition.
Porous FeAl-based intermetallics with different nominal compositions ranging from Fe-40 at% Al to Fe-60 at% Al are prepared by a novel process of thermal explosion (TE) mode. The results show that the Al content significantly affects the combustion behavior of the specimens, the ignition temperature of the Fe-Al intermetallics varies from 641 to 633 C and the combustion temperature from 978 to 1179 C. The porous materials exhibit uniform pore structures with porosities and average pore sizes of 52-61% and 20-25 mm, respectively. The TE reaction is the dominant pore formation mechanism regardless of the alloy composition. However, differences in the porosity and average pore size are observed depending on the Al content. The compressive strength of porous Fe-Al intermetallics is in the range of 23-34 MPa, duly applied as filters. Additionally, a surface alumina layer is formed at the early stage and both of the oxidation process and the sulfidation process follows the familiar parabolic rate law in the given atmosphere, exhibiting excellent resistance to oxidation and sulfidation. These results suggest that the porous Fe-Al intermetallics are promising materials for applications in harsh environments with a high-temperature sulfide-bearing atmosphere, such as in the coal chemical industry.
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