In
a previous article, it was reported that a rather amount of
sulfate end-groups as initiator fragment were buried in the inside
of polystyrene (PS) particles, which were synthesized by emulsion
polymerization with potassium persulfate initiator and nonionic emulsifier
and operated to absorb water from the aqueous medium, resulting in
hollow particles, when the PS emulsion was treated at higher temperature
than the glass transition temperature of PS. In this article, it was
clarified that the water absorption is based on the osmotic pressure
between the outside (aqueous medium) and inside of the PS particles
due to the buried sulfate end-groups.
The silicon steel was cold rolled by using an oil-in-water emulsion for lubricating its surfaces. Oil in water (O/W) emulsion is a lubricant composed of oil in the form of droplets suspended in water. This paper mainly researched on the new emulsion which was prepared by changing the compound proportion between antioxidant 2, 6-Di-tert-butyl-p-cresol (T501) and antirust agent petroleum sodium sulfonate (T702). The corrosion behavior of the emulsion was investigated by weight loss and electrochemical methods. The mechanisms for inhibition of corrosion synergism between T501 and T702 in base oil were studied. The results show that the antirust agent (T702) can effectively forming a layer of adsorption film on the rolled strip surface and this adsorption film can segregate strip surface from air and water. The antioxidant (T501) can capture oxygenic free radical (•OH, RO•, ROO•) and carbon free radical and reduces the trend which emulsion occur oxidation reaction under high temperature and high pressure. The antioxidant plays a minor role in inhibition of corrosion synergism. The results show that the best compound proportion content is 4% antioxidant (T501) and 8% antirust agent (T702), which can effectively increase the anticorrosion effect of emulsion. Meanwhile, the self-corrosion potential and self-corrosion current of the sample is minimal and the self-corrosion current is 1.0226×10-7A/cm2.
Si3N4 (0 and 6 mass%) were added to Al-Al2O3 composite respectively, with phenolic resin as binder, to make Al-Si3N4-Al2O3 unfired composites, which were dried at 200°C for 24h.The creep properties of composites were tested researched under 0.2MPa×50h at 1300°C. The results indicated that the samples put up the features of steady-state creep stage from 25h to 50h; Al4O4C appeared in the corundum matrix with the addition of Al,which improve its creep resistance; when Al and Si3N4 were both existed, sialon phase was formed while Al4O4C was disappeared.
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