Herein, we prepared and compared two water-soluble amphiphilic zein-based nanocarrier systems with avermectin (AVM) payload to enhance pesticide's water-dispersity, foliage wettability, adhesion, anti-UV, and pH-responsive controlled release property. Ethylene glycol diglycidyl ether (EGDE) and diethanolamine (DEA) were utilized to conjugate with hydrophobic zein via a ring-opening reaction and then encapsulated with AVM via a hydrophobic interaction to fabricate a nanopesticide marked as AVM@Zein-EGDE/DEA. For the sake of further improving the nanocarrier's performance, sodium carboxymethyl cellulose (CMC) was grafted with methyl methacrylate (MMA) and 2-hydroxyethyl methacrylate (HEMA) to form a kind of copolymer CMC-g-P(HEMA-MMA), which was applied to conjugate with Zein-EGDE via a ring-opening reaction. Likewise, another nanopesticide system named AVM@Zein-EGDE/CMC-g-P(HEMA-MMA) was obtained through hydrophobic interactions as well as the electrostatic effect. Various techniques were utilized to confirm chemical interaction, thermal behavior, structural characteristics, and stability. The results showed that AVM encapsulated in Zein-EGDE/CMC-g-P(HEMA-MMA) possessed a larger particle size with an average value of 180−254 nm than AVM loaded in Zein-EGDE/DEA with 144−175 nm but had better stability in aqueous solution. Also, AVM loaded in Zein-EGDE/CMC-g-P(HEMA-MMA) enhanced the encapsulation efficiency, and both of them exhibited excellent pH-responsive sustained release behavior. Besides, the former improved wettability on a cucumber leaf surface and enhanced adhesion ability compared to AVM@Zein-EGDE/DEA because of CMC-g-P(HEMA-MMA) with hydrophobic segments. Similarly, anti-UV performance was also enhanced owing to CMC-g-P(HEMA-MMA) as an additional protective layer. More importantly, the encapsulation of Zein-EGDE/DEA and Zein-EGDE/CMC-g-P(HEMA-MMA) as protective barriers for AVM still retained a similar toxicity level. Overall, we demonstrated the proof of concept for the application of amphiphilic zeinbased nanomaterials as aqueous nanocarriers for hydrophobic pesticides.
Orbit accuracy of the transfer orbit and the mission orbit is the basis for the orbit control of all-electric-propulsion Geostationary Orbit (GEO) satellites. Global Navigation Satellite System (GNSS) simulation data are used to analyze the main factors affecting GEO satellite orbit prediction accuracy under the no-thrust condition, and an electric propulsion calibration algorithm is designed to analyze the orbit determination and prediction accuracy under the thrust condition. The calculation results show that the orbit determination accuracy of mission orbit and transfer orbit without thrust is better than 10 m using onboard GNSS technology. The calibration accuracy of electric thrust is about 10−9 m/s2 and 10−7 m/s2 with 40 h and 16 h arc length, respectively, using the satellite self-positioning data of 100 m accuracy to calibrate the electric thrust. If satellite self-positioning data accuracy is at the 10 m level, the electric thrust calibration accuracy can be improved by about one order of magnitude, and the 14-day prediction accuracy of the transfer orbit with thrust is better than 1 km.
The simplebaseline model achieves high performance of human pose estimation with simple network structure. But the model lacks the layer and spatial information fusion. In this paper, we propose DLSAnet, which fuse layers and spatial information efficetively. DLSAnet uses DLA as backbone which has excellent feature extraction capabilities in the field of object detection. In addition, a modified spatial pyramid pooling is introduced to pool and connect multi-scale local area features, allowing the network to learn object features more comprehensively. Using a four-branch SPP module instead of a single-branch SPP module connected by a single hopping layer. This method is effective in alleviating the problem of slow loss drop late in training. Experiments show that DLSAnet can achieve better accuracy.
At present, fossil energy is depleted and environmental pollution is severe. Based on this context, renewable energy has begun to be paid attention to, among which ocean thermal energy conversion (OTEC) has received more and more attention. In this paper, the organic Rankine cycle (ORC) wasted heat power generation system is built. Through the experimental method of controlling variables, the effects of the temperature of the heat source and the flow rate of the working fluid on system performance are explored. The results show that: when the flow rate of the working fluid is constant, as the temperature of the heat source gradually increases, the generating power of the ORC system increases rapidly first and then increases slowly. When the temperature of the heat source remains unchanged and the flow of working fluid gradually increases, the generating power of the ORC system increases first and then decreases. At different temperatures, there is a corresponding optimal working fluid flow that maximizes the system output power, and the higher the temperature, the greater the system output power. Through experiments, it is found that the maximum generating power of the ORC system is 667.55W, the corresponding heat source temperature is 120°C, the working fluid flow is 470.64 kg/h, and the frequency is 90 Hz. The experiment also found that the relationship between the pulse damper frequency and the working fluid flow is linear.
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