The efficient single-photon upconversion photoluminescence (UCPL) feature of lead halide perovskite semiconductors makes it promising for developing laser cooling devices. This is an attractive potential application, but the underlying physics still remains unclear so far. By using the all-inorganic CsPbX 3 (X = Br, I) nanocrystal samples, this phenomenon was investigated by photoluminescence (PL) and timeresolved PL under different temperatures and various excitation conditions. A broad emission band located at the low-energy side of the free exciton (FE) peak was detected and deduced to be from the self-trapped exciton (STE). The lifetime of STE emission was found to be 171 ns at 10 K, much longer than that of FE. The UCPL phenomenon was then attributed to thermal activation of transformation from STEs to FEs, and the energy barrier was derived to be 103.7 meV for CsPbBr 3 and 45.2 meV for CsPb(Br/I) 3 , respectively. The transformation also can be seen from the fluorescence decay processes.
Carbonization of nature-inspired polydopamine can yield thin films with high electrical conductivity. Understanding of the structure of carbonized PDA (cPDA) is therefore highly desired. In this study, neutron diffraction, Raman spectroscopy, and other techniques indicate that cPDA samples are mainly amorphous with some short-range ordering and graphite-like structure that emerges with increasing heat treatment temperature. The electrical conductivity and the Seebeck coefficient show different trends with heat treatment temperature, while the thermal conductivity remains insensitive. The largest room-temperature ZT of 2 × 10 was obtained on samples heat-treated at 800 °C, which is higher than that of reduced graphene oxide.
Noncommutative phase space plays an essential role in particle physics and quantum gravity in the Planck's scale. However, there has not been a direct experimental evidence or observation to demonstrate the existence of noncommutative phase space. We study quantum ring in noncommutative phase space based on the Seiberg-Witten map and give the effective magnetic potential and field coming from the noncommutative phase space, which induces the persistent current in the ring. We introduce two variables as two signatures to detect the noncommutative phase space and propose an experimental scheme to detect the noncommutative phase space as long as we measure the persistent current and the external magnetic flux.
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