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Reducing the high operation temperature of gas sensor to room temperature (RT) have attracted intense interests for its distinct preponderances, including energy‐saving and super stability, which presents great prospects in commercial application. The exciting strategies for RT gas sensing, such as unique materials with activated surface or light activation, do not directly modulate the active ions for gas sensing, limiting the RT gas sensing performances. Here, an active‐ion‐gated strategy has been proposed for RT gas sensing with high performance and low power consumption, in which gas ions in triboelectric plasma are introduced into metal oxide semiconductor (MOS) film to act as both floating gate and active sensing ions. The active‐ion‐gated ZnO nanowires (NWs) array shows a sensitivity of 38.3% to 10 ppm acetone gas at RT, and the maximum power consumption is only 4.5 mW. At the same time, the gas sensor exhibits excellent selectivity to acetone. More importantly, the response (recovery) time of this sensor is as low as 11 s (25 s). It is found that OH−(H2O)4 ions in plasma are the key for realizing RT gas sensing ability, and an accompanied resistive switch is also observed. It is considered that the electron transfer between OH−(H2O)4 and ZnO NWs will forms a hydroxyl‐like intermediate state (OH*) on the top of Zn2+, leading to the band bending of ZnO and activating the reactive O2− ions on the oxygen vacancies. The active‐ion‐gated strategy proposed here present a novel exploration to achieving RT gas sensing performance of MOS by activating sensing properties at the scale of ions or atoms.

CdS nanoparticles with high uniformity have been synthesized through a new liquid-liquid approach, using dimethyl sulfoxide and the mixture of oleyl amine and oleic acid as separate solvents, more convenient inorganic cadmium salt as cadmium source, and sulfur powder as sulfur source. The process can be conducted under mild conditions. It is found that the initial Cd/S molar ratio of precursor plays important role in controlling particle size. Higher concentration of sulfur precursor results in the larger particle size. The obtained colloidal CdS nanocrystals show obvious absorption and fluorescence in visible light region. When using methylene blue as degradation agent, the obtained CdS nanoparticles exhibit high photocatalytic ability.

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