With the development of the refining industry, the treatment of refinery wastewater has become an urgent problem. In this study, a ceramic membrane (CM) was combined with Fenton-activated carbon (AC) adsorption to dispose of refinery wastewater. The effect of the combined process was analyzed using excitation–emission matrix (EEM), ultraviolet-visible (UV-vis) and Fourier transform infrared spectroscopies (FTIR). Compared with direct filtration, the combined process could significantly improve the removal of organic pollution, where the removal rate of the COD and TOC could be 70% and the turbidity removal rate was above 97%. It was found that the effluent could meet the local standards. In this study, the membrane fouling was analyzed for the impact of the pretreatment on the membrane direction. The results showed that Fenton-AC absorption could effectively alleviate membrane fouling. The optimal critical flux of the combined process was increased from 60 to 82 L/(m2·h) compared with direct filtration. After running for about 20 d, the flux remained at about 55 L/(m2·h) and the membrane-fouling resistance was only 1.2 × 1012 m−1. The Hermia model revealed that cake filtration was present in the early stages of the combined process. These results could be of great use in improving the treatment efficiency and operation cycle of refinery wastewater.

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