As a superstars of photovoltaic devices, organic–inorganic hybrid perovskite solar cells (PSCs) have garnered plenty of interest due to their superior character. However, many defects, such as carrier recombination, inferior stability, poor interface contact, have prevented their further development. Here, we demonstrate a novel approach of interface engineering to form a compact perovskite layer with decreased defects on SnO2 film by adding tris­(pentafluorophenyl)­boron (TPFPB) as an interfacial modification layer, which validly improves the interface performance and enhances the crystallinity of MAPbI3. Hence the planar MAPbI3 PSCs with TPFPB modification show fast charge transfer and low trap state density with an enhanced champion power conversion efficiency (PCE) from the original of 16.92% to 19.41%, as well as long-term stability with 80.7% of its initial PCE after 1000 h of aging in N2 atmosphere without encapsulation, while the pristine one only shows 68.9% of the original PCE. The results reveal that TPFPB can be used as an effective interface modification layer for high efficiency and stability PSCs, and it maybe also be used in other devices due to its superior interface modification for high quality crystallinity thin films.

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