We review recent progress achieved in the theoretical description of the interactions, correlations, and phase behavior of concentrated solutions of star polymers, sterically stabilized colloids, and micelles. We show that the theoretical prediction of an ultrasoft, logarithmically diverging effective interaction between the star centers, which has been confirmed by SANSexperiments and computer simulations, lies in the core of a host of unusual phenomena encountered in such systems. These include anomalous structure factors, reentrant melting behavior, as well as a variety of exotic crystal phases. Extensions to polydisperse stars and the role of many-body forces are also discussed. A particular 'mean-field' character of star polymer fluids is presented and it is shown that it manifests itself in the shape and structure of sedimentation profiles of these systems.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.