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The absorption of CO2 on MgO is being studied in depth in order to enhance carbon engineering. Production of carbonate on MgO surfaces, such as MgCO3, for example, has been shown to hinder further carbon lattice transit and lower CO2 collecting efficiency. To avoid the carbonate blocking effect, we mimic the water harvesting nano-surface systems of desert beetles, which use alternate hydrophobic and hydrophilic surface domains to collect liquid water and convey condensed droplets down to their mouths, respectively. We made CO2-philic MgO and CO2-phobic Mg(OH)2 nanocomposites from electrospun nano-MgO by vapor steaming for 2–20 min at 100 °C. The crystal structure, morphology, and surface properties of the produced samples were instrumentally characterized using XRD, SEM, XPS, BET, and TGA. We observed that (1) fiber morphology shifted from hierarchical particle and sheet-like structures to flower-like structures, and (2) CO2 capture capacity shifted by around 25%. As a result, the carbonate production and breakdown processes may be managed and improved using vapor steaming technology. These findings point to a new CO2 absorption technique and technology that might pave the way for more CO2 capture, mineralization, and fuel synthesis options.

The wide bandgap of 2D Mg(OH)2 inhibits its applications in visible-light photocatalytic applications. Besides, its mismatched band alignment to the redox potential of O2/H2O, brings about low efficacy of water-splitting performance. Therefore, to release the powder of 2D Mg(OH)2 in photocatalytic research, we explore anion doping strategies to engineer its electronic structure. Here, anion doping effects on electronic properties of 2D Mg(OH)2 are investigated by using DFT calculations for seven dopants (F, Cl, S, N, P, SO4, and PO4). We found (1) S, N and P doping remarkably reduces its band gap from 4.82 eV to 3.86 eV, 3.79 eV and 2.69 eV, respectively; (2) the band gap reduction is induced by the electron transfer to the dopant atoms; (3) F, Cl, SO4, and PO4 doping shifts its valence band to be lower than the oxidation potential of O2/H2O to render its band structure appropriate for photocatalytic water splitting. These results suggest that not only electrical conductivity of 2D Mg(OH)2 can be increased but also their band structure be aligned by using the proposed anion doping strategy. These results enable a new photocatalytic materials design approach while offering exciting possibilities in applications of high-current electrolysis, chemical gas sensing, and photocatalysis.

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