No abstract

In this work, a novel anti-smudge coating system was developed by using hydroxyl-terminated hyperbranched polyester as a coating precursor, mono-hydroxylterminated poly(dimethylsiloxane) (PDMS) as an antismudge agent, and hexamethylene diisocyanate trimer as a curing agent. The resultant coatings with 0.5 wt % PDMS content incorporated are highly transparent and liquid repellent. They exhibit striking repellency against various liquids and display remarkable self-cleaning performance. Water, hexadecane, salt solution, strong alkali solution, strong acid solution, pump oil, and crude oil could slide off the coated surface without leaving any traces, and the dirt on the coated surface could be readily removed by water or oil. Besides, these coatings show potential application for anti-fingerprint and anti-graffiti due to the exceptional repellency of coated surface against artificial fingerprint liquid, oil-based ink, paint, and water-based smudge. Furthermore, they also possess superb chemical shielding ability and thus endow substrates with remarkable protection against exposure to harsh chemical conditions. Moreover, these coatings are mechanically robust against extensive abrasion, impact, and bending without compromising antismudge properties, and they also exhibit excellent adhesion to various substrates. Therefore, these newly developed coatings have tremendous potential for widespread applications.

No abstract

No abstract

Materials with multiple functions are highly desirable in practical applications. Developing multifunctional nanocomposites by a straightforward process is still a challenge. Here, a versatile nanocomposite has been developed by simple blending and pressing of multiwalled carbon nanotubes (MWCNTs) and modified polydimethylsiloxane (MPDMS). Because of the synergistic effect of MWCNTs and MPDMS, this nanocomposite exhibits outstanding hydrophobic property, striking self-cleaning capability, and excellent chemical stability against strong acid and strong base, which makes it possible to work under wet and even extreme chemical conditions. Besides, because of its flexibility, this nanocomposite can be reshaped, bended, twisted, and molded into on-demand patterns for special applications. Owing to the good distribution of MWCNTs, the nanocomposite shows high conductivity (with a sheet resistance of 86.33 Ω sq–1) and high healing efficiency (above 96.53%) in an electrical field, and it also exhibits outstanding performance in various electrical circuits and flexible electroluminescent devices. Furthermore, the inherent portability, recyclability, and reusability of this nanocomposite make it more convenient and environmentally friendly for practical applications. Thus, our work provides a new strategy to develop a multifunctional nanocomposite, and it shows tremendous potential in flexible electronics.