Gallium oxide (Ga2O3) is an important wide bandgap transparent conductive oxide with many excellent properties, which is widely used in many fields such as catalysis, electroluminescence, biology, and so on. This review mainly introduces the researches on the preparation, properties and applications of gallium oxide nanomaterials. Initially, the preparation of gallium oxide by hydrothermal method has been highlighted and the effects of hydrothermal conditions on the morphologies and sizes of the final products were summarized. Furthermore, the unique properties of gallium oxide in the fields of electricity, gas, heat, and biomedicine are introduced, and the excellent luminescent properties of gallium oxide are emphasized. Additionally, this review mainly introduces the applications of gallium oxide in the fields of catalysis, gas sensors, optoelectronic devices, high voltage electronic devices and biomedicine. Finally, the problems and shortcomings in current research on gallium oxide nanomaterials are discussed and the opinions and prospects are put forward for the future perspective of the research in gallium oxide nanomaterials.

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Ba1+x MoO4 (−0.03 ≤ x ≤ 0.03) ceramics were fabricated by a conventional two-step sintering technique. X-ray diffraction patterns show that there appeared new diffraction peaks when x > 0, which were identified as Ba2MoO5. The Rietveld refinement results indicate that the unit cell volume is the largest at x = −0.02, because it has the lowest packing fraction and covalency. The far-infrared reflectivity (IR) spectra were fitted and analyzed for calculating the intrinsic properties, which comply well with the data obtained from microscopic polarizabilities and damping coefficient angle. The proportion of each mode in the dielectric response demonstrates that the Ba–O8 polyhedra have a decisive role on the dielectric properties. And based on the Raman modes, the internal relations of the structural-properties were revealed with the changes of Ba2+ content.

Pr(Mg1/2Sn1/2)O3 (PMS) ceramic was prepared through a conventional solid-state reaction method. Crystal structure was investigated through X-ray diffraction (XRD), which certificates that the main phase is PMS with monoclinic P2 1/n1 symmetry. Lattice vibrational modes were obtained through Raman scattering spectroscopy and Fourier transform far-infrared reflection spectroscopy. The Raman spectrum active modes were assigned and illustrated, respectively, and then fitted with Lorentzian function. The four modes within the range of 110–200 cm−1 are derived from the F 2g vibrations (A-site cations), and the other three modes (300–430 cm−1) are derived from the F 2g vibrations (B-site cations).The mode with highest frequency above 650 cm−1 is attributed to A 1g-like mode that corresponds to the symmetric breathing of oxygen octahedral. The far-infrared spectrum with seven infrared active modes was fitted using four-parameter semi-quantum models to calculate intrinsic properties (permittivity and loss). F 2u (2) yielded the greatest contribution to dielectric constant and loss, which is mainly performed as the inverted translational vibration of Pr-MgO6 octahedron.

Cr-doped β-Ga2O3 nanorods were systhersized by hydrothermal method, which were characterized in detail so as to analyze the effects of Cr3+ doping on their crystalline quality and photoluminescence property. X-ray...