A new form of governing equations is derived from Hamilton's principle of least action for a constrained Lagrangian, depending on conserved quantities and their derivatives with respect to the time-space. This form yields conservation laws both for non-dispersive case (Lagrangian depends only on conserved quantities) and dispersive case (Lagrangian depends also on their derivatives). For non-dispersive case the set of conservation laws allows to rewrite the governing equations in the symmetric form of Godunov-Friedrichs-Lax. The linear stability of equilibrium states for potential motions is also studied. In particular, the dispersion relation is obtained in terms of Hermitian matrices both for non-dispersive and dispersive case. Some new results are extended to the two-fluid non-dispersive case.
We consider the wetting transition on a planar surface in contact with a semi-infinite fluid. In the classical approach, the surface is assumed to be solid, and when interaction between solid and fluid is sufficiently short-range, the contribution of the fluid can be represented by a surface free energy with a density of the form Φ(ρ S ), where ρ S is the limiting density of the fluid at the surface.In the present paper we propose a more precise representation of the surface energy that takes into account not only the value of ρ S but also the contribution from the whole density profile ρ(z) of the fluid, where z is coordinate normal to the surface.The specific value of the functional of ρ S at the surface is expressed in meanfield approximation through the potentials of intermolecular interaction and some other parameters of the fluid and the solid wall.An extension to the case of fluid mixtures in contact with a solid surface is proposed.
We present a classical approach to a mixture of compressible fluids when each constituent has its own temperature. The introduction of an average temperature together with the entropy principle dictates the classical Fick law for diffusion and also novel constitutive equations associated with the difference of temperatures between the components. The constitutive equations fit with results recently obtained through a Maxwellian iteration procedure in extended thermodynamics theory of multitemperature mixtures. The differences of temperatures between the constituents imply the existence of a dynamical pressure even if the fluids have a zero bulk viscosity. The nonequilibrium dynamical pressure can be measured and may be convenient in several physical situations, such as, for example, in cosmological circumstances where--as many authors assert--a dynamical pressure played a major role in the evolution of the early universe.
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