Bio-oil, although rich in chemical species, is primarily used as fuel oil, due to its greater calorific power when compared to the biomass from which it is made. The incomplete understanding of how to explore its chemical potential as a source of value-added chemicals and, therefore, a supply of intermediary chemical species is due to the diverse composition of bio-oil. Being biomass-based, making it subject to composition changes, bio-oil is obtained via different processes, the two most common being fast pyrolysis and hydrothermal liquefaction. Different methods result in different bio-oil compositions even from the same original biomass. Understanding which biomass source and process results in a particular chemical makeup is of interest to those concerned with the refinement or direct application in chemical reactions of bio-oil. This paper presents a summary of published bio-oil production methods, origin biomass, and the resulting composition.

Biomass thermochemical liquefaction is a chemical process with multifunctional bio-oil as its main product. Under this process, the complex structure of lignocellulosic components can be hydrolysed into smaller molecules at atmospheric pressure. This work demonstrates that the liquefaction of burned pinewood from forest fires delivers similar conversion rates into bio-oil as non-burned wood does. The bio-oils from four burned biomass fractions (heartwood, sapwood, branches, and bark) showed lower moisture content and higher HHV (ranging between 32.96 and 35.85 MJ/kg) than the initial biomasses. The increased HHV resulted from the loss of oxygen, whereas the carbon and hydrogen mass fractions increased. The highest conversion of bark and heartwood was achieved after 60 min of liquefaction. Sapwood, pinewood, and branches reached a slightly higher conversion, with yields about 8% greater, but with longer liquefaction time resulting in higher energy consumption. Additionally, the van Krevelen diagram indicated that the produced bio-oils were closer and chemically more compatible (in terms of hydrogen and oxygen content) to the hydrocarbon fuels than the initial biomass counterparts. In addition, bio-oil from burned pinewood was shown to be a viable alternative biofuel for heavy industrial applications. Overall, biomass from forest fires can be used for the liquefaction process without compromising its efficiency and performance. By doing so, it recovers part of the lost value caused by wildfires, mitigating their negative effects.

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