NITROGUANIDINB 10633. The effects of 36 other inorganic salts, acids and bases have been studied. Salts and oxides of elements of the transition series had various degrees of promoting power. All alkalies accelerated the reaction. Mineral acids had little effect.4. The effect of some substances on the promoting power of ferrous chloride was examined. Large amounts of hydrochloric acid diminished its effectiveness. Sodium nitrate and sodium chloride had very little effect on the acceleration produced by the ferrous chloride, but the latter caused the reaction to proceed slowly beyond the alcohol stage to the hydrocarbon. Sodium nitrite caused a large increase in the induction time and slightly repressed the main part of the reaction.5. Whether a promoter was present or not, and regardless of the nature of the promoter, the first product of the reduction of the aldehydes appeared always to be almost exclusively the corresponding primary alcohol. The formation of hydrocarbon was sometimes observed as a subsequent reaction, but it was always very slow.6. Hypotheses which might account for the mechanism of the promoter effects observed are discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.