Surface pinning effect of the optically isotropic, blue phase liquid crystal (BPLC) has been studied. Polycrystalline, platelet, multi-domain topological defects without surface treatment have been transformed to uniform monodomain in rubbed surfaces of the cell. The operating voltage was reduced by 27%, owing to a dramatic increase in the Kerr constant. Hysteresis was reduced by 63%, whereas the transmission efficiency gets doubled. The surface anchoring effect on the blue phase plays a significant role in the elastic free energy, coherence length and topological defects. BPLC displays with a low operating voltage, and reduced hysteresis can be realized with surface treatment.
Abstract— Three different blue‐phase I liquid‐crystal samples with different grain‐size distribution were studied. Polycrystalline platelet grains reflects light in the visible region and have been observed under a polarizing optical microscope. Green and blue grain areas have been measured and then the statistical histogram by the Gaussian distribution function was fitted and the mean grain size was calculated. The effect of hysteresis on grain size has been compared for the three samples. Hysteresis depends explicitly on the grain‐size distribution. Large grain size has revealed less hysteresis, while small grain size depicted pronounced hysteresis.
The effect of scintillator particle size on high-resolution X-ray imaging was studied using zinc tungstate (ZnWO4) particles. The ZnWO4 particles were fabricated through a solid-state reaction between zinc oxide and tungsten oxide at various temperatures, producing particles with average sizes of 176.4 nm, 626.7 nm, and 2.127 μm; the zinc oxide and tungsten oxide were created using anodization. The spatial resolutions of high-resolution X-ray images, obtained from utilizing the fabricated particles, were determined: particles with the average size of 176.4 nm produced the highest spatial resolution. The results demonstrate that high spatial resolution can be obtained from ZnWO4 nanoparticle scintillators that minimize optical diffusion by having a particle size that is smaller than the emission wavelength.
Sung-Tae Shin (2012) Emergence of a novel optically isotropic transient state with low frequency in a blue phase liquid crystal mixture, Liquid Crystals, 39:2, 231-237,The electro-optical hysteresis characteristics in a blue phase liquid crystal system showing multi-domain platelet type body-centred cubic (BP-I) structure at different levels of applied electric field have been investigated. The BP-I state possesses a large degree of hysteresis due to its compact body-centred cubic structure. The hysteresis behaviour is discussed in the context of simulation and theoretical studies reported earlier. When the cell is driven with a low frequency square wave, a novel optically isotropic state with high value of the Kerr constant has been observed. Hysteresis and response time both show relatively lower values in this state with respect to the multi-domain BP-I state.
Nanocomposites comprising high-density polyethylene (HDPE) and boehmite (BA) nanoparticles were prepared by melt blending and subsequently irradiated with electrons. Electron irradiation of HDPE causes crosslinking and, in the presence of BA, generates ketone functional groups. The functional groups can then form hydrogen bonds with the hydroxyl groups on the surface of the BA. Additionally, if the BA is surface modified by vinyltrimethoxysilane (vBA), it can covalently bond with the HDPE by irradiation-induced radical grafting. The strong covalent bonds generated by electron beam irradiation allow the desirable properties of the nanofiller to be transferred to the rest of the nanocomposite. Since EB irradiation produces a great number of strong covalent bonds between vBA nanoparticles and HDPE, the modulus of elasticity, yield strength, and resistance to thermal shrinkage are enhanced by electron irradiation.
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