a b s t r a c t U-Pb single zircon crystallization ages were determined using TIMS and sensitive high resolution ion microprobe (SHRIMP) on samples of granitoid rocks exposed in the Serrinha nucleus granite-greenstone terrane, in NE Brazil. Our data show that the granitoid plutons can be divided into three distinct groups. Group 1 consists of Mesoarchaean (3.2-2.9 Ga) gneisses and N-S elongated TTG (Tonalite-Trondhjemite-Granodiorite) plutons with gneissic borders. Group 2 is represented by ca. 2.15 Ga pretectonic calc-alkaline plutons that are less deformed than group 1. Group 3 is ca. 2.11-2.07 Ga, late to post-tectonic plutons (shoshonite, syenite, K-rich granite and lamprophyre). Groups 2 and 3 are associated with the Transamazonian orogeny. Xenocryst ages of 3.6 Ga, the oldest zircon yet recorded within the São Francisco craton, are found in the group 3 Euclides shoshonite within the Uauá complex and in the group 2 Quijingue trondhjemite, indicating the presence of Paleoarchaean sialic basement.Group 1 gneiss-migmatitic rocks (ca. 3200 Ma) of the Uauá complex constitute the oldest known unit. Shortly afterwards, partial melting of mafic material produced a medium-K calc-alkaline melt, the younger Santa Luz complex (ca. 3100 Ma) to the south. Subsequent TTG melts intruded in different phases now exposed as N-S elongated plutons such as Ambrósio (3162 ± 26 Ma), Araci (3072 ± 2 Ma), Requeijão (2989 ± 11 Ma) and others, which together form a major part of the Archaean nucleus. Some of these plutons have what appear to be intrusive, but are probably remobilized, contacts with the Transamazonian Itapicuru greenstone belt. The older gneissic rocks occur as enclaves within younger Archaean plutons. Thus, serial additions of juvenile material over a period of several hundred m.y. led to the formation of a stable micro-continent by 2.9 Ga. Evidence for Neoarchaean activity is found in the inheritance pattern of only one sample, the group 2 Euclides pluton.Group 2 granitoid plutons were emplaced at 2.16-2.13 Ga in a continental arc environment floored by Mesoarchaean crust. These plutons were subsequently deformed and intruded by late to post-tectonic group 3 alkaline plutons. This period of Transamazonian orogeny can be explained as a consequence of ocean closure followed by collision and slab break-off. The only subsequent magmatism was kimberlitic, probably emplaced during the Neoproterozoic Braziliano event, which sampled older zircon from the basement.
Blue sodalite syenite is a rare rock, and the Southern Bahia Alkaline Province (SBAP) is the only place in Brazil where economic deposits are found. This province forms part of the Archaean to Paleoproterozoic São Francisco craton, and contains a few batholiths, a large number of stocks and hundreds of dykes. Its southern part lies close to the tectonic contact between the craton and the Neoproterozoic Araçuaí mobile melt. Blue sodalite-bearing syenites are found in almost all the igneous bodies of the SBAP as dykes or pegmatitic masses hosted by nepheline syenite. Economically viable quantities for the production of dimension stones are found only in the Floresta Azul alkaline complex, the Itaju do Colônia and Rio Pardo stocks and the Itarantim batholith. U-Pb ages obtained for titanite from Itaju do Colônia (732 ± 8 Ma) and Rio Pardo (714 ± 8) and Pb-Pb evaporation ages of zircon from Floresta Azul (696 ± 3 Ma) and Itarantim (722 ± 5 Ma). The geochronology of the SBAP shows that the anorogenic alkaline magmatism persisted for at least 58 Ma, demonstrating an extensional tectonic environment in the southern part of the São Francisco craton at this time. The data show that the rift phase which preceded the formation of the Araçuaí orogen was active until at least 700 Ma. The reported ages are similar to those found for the nepheline syenite host bodies, which supports the conclusions of the previous petrologic study demonstrating that blue sodalite is formed during the crystallization of these bodies. Two different processes are involved. In the magmatic process, sodalite occurs as disseminated and interstitial crystals among alkali feldspar
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