Rationally developing an intelligent tool for highcontrast fluorescence imaging of latent fingerprints (LFPs) is gaining much concern in many applications such as medical diagnostics and forensic investigations. Herein, the off−on fluorescent polymer micelles (PMs) have been rationally designed and synthesized for high-contrast fluorescence imaging of LFPs through the cross-linking reaction of hydrazine (N 2 H 4 ) and aldehyde group of polymer. Excitingly, the cross-linking (N 2 H 4 ) induced emission of PMs has the property of aggregation-induced emission (AIE) and excited state intramolecular proton transfer (ESIPT), which could effectively address the notorious aggregation-caused quenching (ACQ) effects of conventional organic dyes. In addition, the cross-linking strategy can not only improve structural stability of PMs but also enhance its fluorescence brightness. The experiment results demonstrated that PMs showed high water dispersibility (100% aqueous solution), high selectivity, large Stokes shift (∼150 nm), good photostability, and excellent long-term stability. Because of the hydrophobic interaction between the PMs and fingerprint components, the PMs preferentially adhered onto the ridges of fingerprint, and then cross-linking (N 2 H 4 ) induced emission properties endowed the PMs for high-contrast imaging of LFPs in different substrates, especially the levels 1−3 details of LFPs. We expect that this strategy will provide vital support for LFPs technology.

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