An enantioselective hydrosilylation of prochiral ketones was achieved by using a catalytic amount of the readily accessible and air-and moisture-stable iridium complex [IrClA
The air‐ and moisture‐stable isoleucinol‐derived iridium carbene complex IRI in combination with AgBF4 efficiently catalyzes the stereoselective reduction of a variety of acetophenone derivatives and analogues at room temperature.
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