Spin fluctuation-induced superconductivity in two-dimensional organic
compounds such as \kappa-(ET)_2-X is investigated by using a simplified dimer
Hubbard model with right-angled isosceles triangular lattice (transfer matrices
-\tau, -\tau^\prime). The dynamical susceptiblity and the self-energy are
calculated self-consistently within the fluctuation exchange approximation and
the value for T_c as obtained by solving the linearized Eliashberg-type
equations is in good agreement with experiment. The pairing symmetry is of
d_{x^2-y^2} type. The calculated (U/\tau)-dependence of T_c compares
qualitatively well with the observed pressure dependence of T_c. Varying the
value for \tau^\prime/\tau from 0 to 1 we interpolate between the square
lattice and the regular triangular lattice and find firstly that values of T_c
for \kappa-(ET)_2-X and cuprates scale well and secondly that T_c tends to
decrease with increasing \tau^\prime/\tau and no superconductivity is found for
\tau^\prime/\tau=1, the regular triangular lattice.Comment: 4 pages, 6 eps figures, uses jpsj.st
The transport properties of a biphenyl dithiol (BPD) molecule sandwiched between two gold electrodes are studied using the nonequilibrium Green's function method based on the density functional theory. In particular, their dependence on the dihedral angle (phi=90 degrees -180 degrees ) between two phenyl rings is investigated. While the dihedral-angle dependence of the density of states projected on the BPD molecular orbitals is small, the transport properties change dramatically with phi. The transmission at the Fermi energy exhibits a minimum at phi=90.0 degrees and greatly increases with phi. The ratio of the maximum obtained at phi=180 degrees to the minimum exceeds 100. As an application of this characteristic transport behavior, a BPD molecule functionalized with NH(2) and NO(2) groups is considered. It is found that this molecule works as a nanorectifier.
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