As the size of modern infrastructure increases, novelties related to mass concrete mixtures including supplementary cementitious materials (SCMs) become critical. The effects of binary and ternary cement replacement mixtures including metakaolin, silica fume, ground calcium carbonate, granulated blast furnace slag, and fly ash on the rate and amount of heat generated in concrete mixtures are investigated. Twenty three binary and ternary mixtures with a water-to-cementitious binder ratio of 0.43 are evaluated. Between 15% and 45% cement replacement by weight is considered. Results indicate that binary mixtures containing metakaolin or silica fume offer no advantage in reducing the amount of heat but increase compressive strength by 20%. On contrary, ternary mixtures, including two pozzolanic materials, provide 15% reduction in the amount of heat evolution without compromising strength. This reduction is observed regardless of alumina (Al) or silica (Si) content in pozzolanic materials when 45% cement is replaced with a combination of slag and metakaolin, or slag and silica fume. Furthermore, the effect of increased calcium (Ca) content is investigated. It is concluded that ternary mixtures with decreased Ca/(Al+Si) ratio reduce internal temperature in mass concrete structures and are less likely to be exposed to the threshold temperature for delayed ettringite formation.

Abstract:Metakaolin is the only major natural pozzolan to be specified for use as a supplementary cementitious material in the United States. As a result, the metakaolin market for concrete has grown dramatically in the past 20 years. As of now, the specifications of up to 16 state departments of transportation allow for the use of commercially-available and high-reactivity metakaolin products. However, to the best of the authors' knowledge, no study has been performed to evaluate whether these products are comparable in their performance. Three commercially-available (U.S.) metakaolin products, each replacing 10%, 15%, and 20% of the cement content in concrete and mortar mixtures are studied. Concrete mixtures contained a cementitious content of 422 kg/m 3 , a coarse aggregate fraction of 985 kg/m 3 , and a water-to-cementitious ratio equal to 0.43. Varying levels of a superplasticizer were used to maintain a uniform workability between mixtures. Each mixture was subjected to the following tests: compression, split-cylinder tension, modulus of rupture, dynamic elastic modulus, rapid chloride-ion penetrability, alkali-silica reactivity, sulfate resistance, the coefficient of thermal expansion, and drying shrinkage. Benefits from the inclusion of metakaolin were highly product-dependent and include increases in mechanical strength. All metakaolin supplemented concrete mixtures benefitted from decreased permeability and increased resistance to chemical attacks, with the exception of the sulfate resistance of mortars including a metakaolin product with high fineness. The inclusion of any metakaolin at any replacement level increased the coefficient of thermal expansion of concrete specimens. Reasons for difference in performance between products are discussed, and predictors of quality are recommended.

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