In this study, an efficient strategy for the synthesis of solvent titanium dioxide and titanium dioxide/graphitic carbon nitride (TiO2/g-C3N4) heterostructure photocatalyst was applied to fabricate a kind of visible-light-driven photocatalyst. The obtained samples were  characterised  by  means of  X-ray diffraction, infrared spectroscopy, ultraviolet–visible spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy and photoluminescence. The heterostructure shows higher absorption edge towards harvesting more solar energy compared with pure TiO2 and pure g-C3N4 respectively. The  photocatalytic  behaviour  under  visible light  and  kinetics of  the TiO2/g-C3N4 catalyst via methylene blue degradation were addressed. The results showed that the introduction of solvent titanium dioxide  into g-C3N4 enhanced  the  photocatalytic activity in  the  visible  light region.  TiO2/g-C3N4 is  potential  visible  light  driven photocatalyst  for  the  organic substances degradation in aqueous solutions.