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Solvent extraction experiments were conducted to recover pure Pt(IV) and Rh(III) from the chloride leach liquor of glass industry scraps containing a small amount of Fe(III) using Alamine 336, TOPO, TBP and Cyanex 923. The Pt(IV) and Fe(III) were selectively extracted by Cyanex 923 leaving Rh(III) in the raffinate, while only Fe(III) was extracted by TBP. The Pt(IV) in the loaded Cyanex 923 phase was first selectively stripped over Fe(III) by NaSCN and then the remaining Fe(III) was stripped by HCl solution. The Fe(III) in the loaded TBP phase was easily stripped by dilute HCl solution. The McCabe-Thiele diagrams for the extraction of Pt(IV) by Cyanex 923 and of Fe(III) by TBP were constructed. Based on the obtained results, a flowsheet for the separation of three metals from the real leaching solution of glass industry scraps was proposed.

Cyanex 301 and 5,8-diethyl-7-hydroxyldodecane-6-oxime (LIX 63) can selectively extract Pd(II) over Pt(IV) from concentrated hydrochloric acid solutions. Therefore, solvent extraction experiments have been performed by extractant mixtures containing either Cyanex 301 or LIX 63, and the extraction behavior of Pd(II) was compared. Among the mixtures of Cyanex 301, the highest synergistic enhancement coefficient was achieved by mixing Cyanex 301 and trioctylphosphine oxide (TOPO). However, it was very difficult to strip the Pd(II) from the loaded mixture phase. Among the mixtures of LIX 63, the mixture of LIX 63 and alamine 336/TOPO enhanced the extraction of Pd(II). Although the synergistic coefficient by Cyanex 301 + TOPO was higher than that by LIX 63 + Alamine 336, the Pd(II) in the loaded mixture phase of LIX 63 and alamine 336 was easily stripped by thiourea.

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