In this study, synthetic silicone rubber (SR) and Bi2O3 micro- and nanoparticles were purchased. The percentages for both sizes of Bi2O3 were 10, 20 and 30 wt% as fillers. The morphological, mechanical and shielding properties were determined for all the prepared samples. The Linear Attenuation Coefficient (LAC) values of the silicon rubber (SR) without Bi2O3 and with 5, 10, 30 and 30% Bi2O3 (in micro and nano sizes) were experimentally measured using different radioactive point sources in the energy range varying from 0.06 to 1.333 MeV. Additionally, we theoretically calculated the LAC for SR with micro-Bi2O3 using XCOM software. A good agreement was noticed between the two methods. The NaI (Tl) scintillation detector and four radioactive point sources (Am-241, Ba-133, Cs-137 and Co-60) were used in the measurements. Other shielding parameters were calculated for the prepared samples, such as the Half Value Layer (HVL), Mean Free Path (MFP) and Radiation Protection Efficiency (RPE), all of which proved that adding nano-Bi2O3 ratios of SR produces higher shielding efficiency than its micro counterpart.

We prepared red clays by introducing different percentages of PbO, Bi2O3, and CdO. In order to understand how the introduction of these oxides into red clay influences its attenuation ability, the mass attenuation coefficient of the clays was experimentally measured in a lab using an HPGe detector. The theoretical shielding capability of the material present was obtained using XCOM to verify the accuracy of the experimental results. We found that the experimental and theoretical values agree to a very high degree of precision. The effective atomic number (Zeff) of pure red clay, and red clay with the three metal oxides was determined. The pure red clay had the lowest Zeff of the tested samples, which means that introducing any of these three oxides into the clay will greatly enhance its Zeff, and consequently its attenuation capability. Additionally, the Zeff for red clay with 10 wt% CdO is lower than the Zeff of red clay with 10 wt% Bi2O3 and PbO. We also prepared red clay using 10 wt% CdO nanoparticles and compared its attenuation ability with the red clay prepared with 10 wt% PbO, Bi2O3, and CdO microparticles. We found that the MAC of the red clay with 10 wt% nano-CdO was higher than the MAC of the clay with microparticle samples. Accordingly, nanoparticles could be a useful way to enhance the shielding ability of current radiation shielding materials.