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International audienceWe report revisited experimentally retrieved and theoretically calculated He-broadened Lorentz half-width coefficients and He- pressure-shift coefficients of 45 carbon monoxide transitions in the 1<--0 band. The spectra analyzed in this study were recorded over a range of temperatures between 79 and 296 K. The He-broadened line parameters and their temperature dependences were retrieved using a multispectrum nonlinear least squares analysis program. The line shape models used in this study include Voigt, speed dependent Voigt, Rautian (to take into account confinement narrowing) and Rautian with speed dependence, all with an asymmetric component added to account for weak line mixing effects. We were unable to retrieve the temperature dependence of line mixing coefficients. A classical method was used to determine the He-narrowing parameters while quantum dynamical calculations were performed to determine He-broadening and He-pressure shifts coefficients at different temperatures. The line mixing coefficients were also derived from the exponential power gap law and the energy corrected sudden approximation. The current measurements and theoretical results are compared with other published results, where appropriate

The spectral line parameters of carbon dioxide have been measured in the laser band I (00011 ← 10001) centred at 10.4 μm. The spectra were recorded at room temperature using the spectroscopic instrumentation at the far-infrared beamline, Canadian Light Source, Saskatoon, Sask. The spectral line intensities, air- and self- broadened Lorentz half widths, and pressure-induced shift coefficients were retrieved for 48 spectral lines using a multispectrum fit technique (Benner et al. J. Quant. Spectrosc. Radiat. Transfer, 53, 705 (1995)). Line parameters were retrieved using the Voigt and speed-dependent Voigt models. The deviations between our results and other results reported in the literature and in the HITRAN08 (Rothman et al. J. Quant. Spectrosc. Radiat. Transfer, 110, 533 (2009)) database were examined and discussed. The effect of errors in fitting channel spectra parameters was examined and found to be mitigated by the inclusion of channels in the multispectral fit.