La1-xCaxCrO3 (0.1≤ x ≤ 0.4) is usually used as interconnect material for solid oxide fuel cells
(SOFCs). In this paper, composite material, the two-phase mixtures of face-centered cubic fluorite
structure CayCe1-yO2-y (0 ≤ y≤ 0.2) and orthorhombic perovskite structure [Sm(Eu,Gd)]1-zCazCrO3 (0 < z <
0.3), was prepared by an auto-ignition process in which mixed rare earth oxides (Sm2O3, Gd2O3, Eu2O3
and CeO2) are substituted for La2O3 in La1-xCaxCrO3. The direct current (DC) four-probe technique
measurement indicated that the electrical conductivities of specimens increased along with the increase of
Ca2+ content (x), especially when x=0.3 and 0.4. The material (x=0.4, about 94% relative density) showed
excellent electrical conductivities of 48 Scm-1 in air and 13 Scm-1 in H2 (purity 99.999%) at 700°C
respectively, which is about 3 times as high as that of La0.7Ca0.3CrO3.
Perovskite Sm1-xSrxCoO3 ceramics have been successfully prepared by gelcasting from oxides
and carbonate powders, which were characterized by sintering the gels cast from a suspension of
low-solubility metallic oxide precursors and organic monomers. The porosity, pore size, microstructure
and electrical conductivity of the obtained Sm1-xSrxCoO3 ceramics were also investigated. It has been
shown that single Sm1-xSrxCoO3 perovskite phase forms at a relatively low calcination temperature of
1000°C. Especially, porous Sm1-xSrxCoO3 ceramics with homogeneous microstructure can be obtained by
controlling sintering process of the gelcasts. In addition, the Sm1-xSrxCoO3 ceramics show good electrical
conductivity, which can meet the demand for solid oxide fuel cell cathode application.
To the old cement concrete pavement which lost the overall loading capacity and large areas are damaged, by using rubblization technology to shocks, crushing and compaction it, pouring the warm-mix asphalt sealing, formed less than 60mm size of flexible base of gravel and paved with warm-mix asphalt pavement on this base. This article is about analysis of interlinear stresses of pavement structure and production cost analysis of mixture on this combination structure. Proved that the structure could in-place recycling, solving the environmental issues of dropped cement pieces garbage. Mix in mixture, spreading process of reducing harmful gas emissions, can save more than 30% of construction costs.
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