The research aimed to study 24 rock slope surfaces along the road around Hon Lon Island, Kien Hai district, Kien Giang province, Vietnam. The analytical results have determined slope failure, wedge failure, and toppling, which occurred on almost slope surface and the average percentage of plane failure is the largest. The average percent of plane failure is 19.23%, the wedge failure is 15.35%, and the toppling fault is 6.73%. Besides, the analytical results have also identified the slope surfaces which can be the key blocks: ND-13, 18, 23, 25, 34, 37, 45, 51, 62, 63. The other analytical results show that the existence of key blocks at the rock slope surfaces in the N-S direction, dip to E at the survey locations: ND-13, 23, 63 and dip to W at the survey locations: ND-37, 45; in the NE-SW direction, dip to SE at the survey locations: ND-15, 62 and dip to NW at the survey locations: ND-18, 34; in the NW-SE direction, dip to SW at the survey location ND-51. These results have important significance to support for protecting slope surface safety.