Experimental radiative lifetimes for 34 odd-parity levels belonging to 4d 35p and 4d 25s5s configurations of Nb ii were measured by the time-resolved laser-induced fluorescence method. The results range from 2.2 to 11.5 ns, and 30 of them were reported for the first time, as far as we know. The theoretical radiative lifetimes for these levels were also calculated by the pseudorelativistic Hartree–Fock method including core-polarization contributions (HFR+CPOL) and the fully relativistic multiconfiguration Dirac–Hartree–Fock method, and branching fractions for these levels were also calculated by HFR+CPOL. By combining the experimental lifetimes and the calculated branching fraction values, the semiempirical transition probabilities and oscillator strengths for 389 Nb ii lines were obtained.

Using the time-resolved laser-induced fluorescence technique, the radiative lifetimes for 15 odd-parity levels from 47,003 to 61,475 cm−1 in Ir ii were measured. To the best of our knowledge, 11 lifetime results among these levels are reported for the first time, and hence they should be a good complement to the measured lifetime data of 10 levels previously published in the literature. The pseudorelativistic Hartree–Fock including core-polarization corrections method was used to calculate the lifetimes and branching fractions (BFs) of the investigated energy levels. Combining the experimental lifetime with the theoretical BFs, the transition probabilities and oscillator strengths for 124 transitions were determined.