The low efficiency of thermal conductive filler is an unresolved issue in the area of thermal conductive polymer composites. Although it is known that minimizing phonon or electron interfacial scattering is the key for achieving high thermal conductivity, the enhancement is generally limited by preparation methods that can yield the ideal morphology and interfaces. Herein, low temperature expandable graphite (LTEG) is added into a commercial impact modifier (Elvaloy4170), which is then coated onto poly(butylene terephthalate) (PBT) particles with various sizes at millimeter scale between their melting temperatures. Thus, macroscopic segregated filler networks with several considerations are constructed: high LTEG loading leads to a short distance between fillers and a robust filler network; continuous Elvaloy-LTEG phase leads to a continuous filler network; and good interaction among filler and matrix leads to good interfacial interaction. More importantly, the rather large size of PBT particles provides the filler networks with low specific interfacial area, which minimizes the interfacial scattering of phonons or electrons. Relative to homogeneous composites with an identical composition, the thermal conductivity is enhanced from 6.2 to 17.8 W/mK. Such an enhancement span is the highest compared with results reported in the literature. Due to possible "shortcut" behavior, much higher effectiveness can be achieved for the current system than found in literature results when the Elvaloy-LTEG phase is considered as filler, with the effectiveness even exceeding the upper limit of theoretical calculation for highly loaded Elvaloy-LTEG phase with relatively large PBT particle sizes. This could provide some guidelines for the fabrication of highly thermal conductive polymer composites as well as multifunctional polymer composites.
A high filler content is often needed in polymer composite-based
thermoelectric (TE) films to improve their performance. Nevertheless,
this often leads to poor processability and poor mechanical performance.
Herein, a biomimetic approach is adopted to facilitate the filler
content up to 90.5 wt % in free-standing and flexible n-type PVDF/Ag2Se TE films, where PVDF dendricolloids are a solution mixed
with Ag2Se nanowires (NWs), followed by filtration. These
soft dendric nanoparticles within PVDF dendricolloids have high adhesivity
and strong network-building ability, which allows the formation of
“grapevine-grape”-like networks with soft dendritic
particles and inorganic TE fillers as “grapevine” and
“manicure finger grapes”, respectively. The maximum
power factor of 189.02 μW m–1 K–2 is achieved for a PVDF/Ag2Se mass ratio of 1:9.5 at 300
K. Meanwhile, excellent flexibility with only 15.8% decrease in electrical
conductivity after 1000 bending cycles was observed. These properties
at such a high filler content are attributed to the long-range grapevine-like
network of soft PVDF dendritic particles and entanglement between
numerous Ag2Se NWs. This work carves a path to fabricate
high-performance free-standing flexible n-type TE composite films
as well as other functional polymer composites requiring high inorganic
filler loading.
Single-atom sites (SASs) are commonly stabilized and influenced by neighboring atoms in the host; disclosing the structure-reactivity relationships of SASs in water electrolysis is one of the grand challenges originating from the tremendous wealth of support materials with complex structures. Through a multidisciplinary view of the design principles, synthesis strategies, characterization techniques, and theoretical analysis of structure-performance correlations, this timely Review is dedicated to summarizing the most recent progress in tailoring bond microenvironments on different supports and discussing the reaction pathways and performance advantages of different SAS structures for water electrolysis. The essence and mechanisms of how SAS structures influence electrocatalysis and the critical requirements for future developments are discussed. Finally, the challenges and perspectives are also provided to stimulate the practical, widespread utilization of SAS catalysts in water-splitting electrolyzers.
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